fe基磁性纳米颗粒的制备与性能分析 word格式.docxVIP

Preparation and Magnetic Performance research of Fe-based Magnetic NanoparticlesAbstractFePt alloy nanoparticles with different components, Fe3O4 magnetic nanoparticles, and FePt- Fe3O4 nanocomposite particles were synthesized by thermal decomposition method under high boiling temperature solvents. We chose platinum acetylacetonate (Pt(acac)2) as the precursor of Pt, and iron pentacarbonyl (Fe(CO)5) as the precursor of Fe, and used two different kinds of surfactants, oleic acid (C17H33COOH) and oil amine(C18H35NH2,), simultaneously. Several techniques, for example, Laser particle size analyzer, X-ray diffraction (XRD), Inductively coupled plasma emission spectrometer (ICP), High-resolution transmission electron microscopy (HRTEM), Vibrating sample magnetometer (VSM) and Superconducting quantum interface (SQUID) have been employed to study the composition, morphologies, size distributions, phase constitution, microstructure and magnetic properties. The mechanism of nanoparticle growth is also discussed for the Fe3O4 magnetic nanoparticles in different preparing processes. The main achievements are as follows:(1). The monodisperse FePt nanoparticles have been synthesized successfully by thermal decomposition, and all the particle size are less than 10 nm (6 nm~8 nm). After annealing at 700 oC for 1 hour on the silicon slice, the FCC structure for as-prepared FePt nanoparticle has changed to FCT structure, and the coercivity is large as 1 T for the Fe-Pt composition ration with 1:1.0.(2). The monodisperse, morphology/size-controllable Fe3O4 nanoparticles have been synthesized successfully by thermal decomposition. The study shows that the growth of Fe3O4 nanoparticles underwent two processes: one is the so-called nucleation stage near the decomposition temperature of precursor, the other is the subsequent growing up of the crystal under the refluxing of the solution near the boiling point of the solvent. The two surfactants, oleic acid and oleylamine, play different ro