dna纳米复合材料的制备及性能分析word格式论文.docxVIP

AbstractDNA makes up the genetic component of almost all living organisms. Since the discovery of the double-helical structure by Waston and Crick, the biochemical property, structure and morphology of DNA have been widely investigated. Recently with the development of nanotechnology and the synthesis of functional nanomaterials, researchers have devoted to using biomolecules with ordered structure as templates to prepare biofunctional nanomaterials. DNA was considered as the ideal template to prepare 1D and 2D nanomaterials, because of its thermal stability, mechanical rigidity, and capability of assembling into periodically patterned superstructures, such as filaments, nanoribbons and nanogrids. In this article we extented DNA nanotechnology. As a result nanomaterials with different morphologies have been prepared. Also self-assembly multilayer films containing DNA has been investigated.The main contents of this thesis are as follows:Photochemical synthesis is a green method to prepare nanomaterials because no treatment procedure, such as removing the template used, separating byproducts and so on, were needed during the process. Here firstly we developed a simple method to prepare gold and silver nanoparticles. During the process Tris-EDTA(TE) was chosen as photosensitizer. The mixed solution of TE and HAuCl4(or AgNO3) were exposed to UV light, resulting in the preparation of gold (or silver) nanoparticles which are all spherical. Transmission Electron Microscopy(TEM), UV-vis spectroscopy (UV-vis), Dynamic laser light scattering (DLS) and X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD) indicated that TE acted as stabilizer and photosensitizer. Nanoparticles with different diameters were prepared by adjusting the irradiation time. It can be inferred from the bactericidal activity experiments that the bactericidal efficiency of the silver nanoparticles obtained is higher than 95% within 30 minutes. This method have potential industrial applicatio