er3yb3 er3ho3掺杂材料的宽带转光与协同效应word格式论文.docx

AbstractWith the rapid development of society, the excessive consumption of energy which lead to the coal, oil, natural gas and other resources on earth quickly dried up. So, finding new renewable energy becomes the current urgent problems to be solved. Solar energy as a clean, pollution-free, the renewable energy, has arising much attention. Therefore, the use of electric energy production by solar cells are an effective way to solve the energy crisis. However, the photoelectric conversion efficiency of solar cells is still low. because the solar cells cannot make full use of sunlight. Solar cells can only absorb sunlight in the visible, and near-ultraviolet of the highest energy and near-infrared light of highest proportion of sunlight cannot be absorbed. Consequently, in order to overcome this drawback of solar cells, people thought of using rare-earth photoluminescence material to go with sun light. Which can convert the light of unavailable into available for solar cells, so as to improve the photoelectric conversion efficiency of solar cells. However, light conversion material for solar cells are also still has many shortcomings, we still need to improve the performance of light conversion material.Firstly,Yb(Er)F3 nanoparticles absorbed with ZnO sheet were prepared via two-step co-precipitation method followed with thermal oxidation. In the ZnO/Yb(Er)F3 composite phosphor, ZnO can efficiently absorb ultraviolet photons of250 nm-380 nm and transfer its absorbed photon energy to Er3+ ions in fluorideparticles. A followed quantum cutting between Er3+-Yb3+ couples in the fluoride takes place, down-converting an absorbed ultraviolet photon into two photons of 650 nm and 980 nm radiations. The composite phosphor combines the wide wavelength absorption range and high absorption cross-section of ZnO with high quantum cutting efficiency of Er3+-Yb3+ co-doped fluoride, showing potential application in the enhancement of Si solar cell efficiency.Secondly, SiO2–PbF2–E