Chapter 5-new Ideal Reactors for a Single Reaction 化学反应工程 讲解材料.pptVIP

Chemical Reaction Engineering;Chemical Reaction Engineering;Chemical Reaction Engineering;Batch Reactor;Chemical Reaction Engineering;Chemical Reaction Engineering;The Mixed Flow Reactor, or MFR ( Fig.5.1c) ;;Chemical Reaction Engineering;The steady and unsteady operation;For these reasons, we often try to design real reactors so that their flows approach these ideal situations. ;5.1 IDEAL BATCH REACTOR ;Evaluating the terms of Eq.1, we find ;By replacing these two terms in Eq.1, we obtain ;This equation may be simplified for a number of situations. If the density of the fluid remains constant, we obtain ;For all reactions in which the volume of reacting mixture changes proportionately with conversion, such as in single gas-phase reactions with significant density changes, Eq.3 becomes ;Chemical Reaction Engineering;Space-Time and Space-Velocity;Space-velocity: ;If the specified condition is the actual condition of the stream entering the reactor, the relation between ? and s and the other pertinent variables is ;5.2 STEADY-STATE MIXED FLOW REACTION ;Figure 5.3 Notation(符号) for a mixed reactor. ;As shown in Fig.5.3, if is the molar feed rate of component A to the reactor, then considering the reactor as a whole we have ;which on rearrangement becomes ;More generally, if the feed on which conversion is based, subscript 0, enters the reactor partially converted, subscript i, and leaves at conditions given by subscript f , we have ;For the special case of constant-density systems XA= 1- CA / CA0 , in which case the performance equation for mixed reactors can also be written in terms of concentrations or ;Figure 5.4 Graphical representation of the design equations for mixed flow reactor. ;EXAMPLE 5.1 REACTION RATE IN A MIXED FLOW REACTOR ;Figure E5.1 ;SOLUTION ;EXAMPLE 5.2 KINETICS FROM A MIXED FLOW REACTOR ;SOLUTION ;The conversion for each run is then calculated and tabulated in column 4 of Table E5.2. ;From the performance equatio