结合可控缩聚和“活性”可控自由基聚合方法合成嵌段和梳状共聚物-synthesis of block and comb copolymers by combination of controllable polycondensation and.docxVIP

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结合可控缩聚和“活性”可控自由基聚合方法合成嵌段和梳状共聚物-synthesis of block and comb copolymers by combination of controllable polycondensation and.docx

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结合可控缩聚和“活性”可控自由基聚合方法合成嵌段和梳状共聚物-synthesis of block and comb copolymers by combination of controllable polycondensation and

结合可控缩聚和“活性”/可控自由基聚合方法合成嵌段和梳状共聚物英文摘要Preparation of Block and Comb-Copolymers via Combination of Chain-Growth Polycondensation and LRPAbstractIn this thesis, block copolymers and comb-copolymers were prepared via combination of chain-growth polycondensation and ―living‖/controlled radical polymerization (LRP). The details are summarized as follows:Synthesis of block copolymers via combination of chain-growth polycondensation and LRP. The initiator, 4-(6-(4-(ethyl benzoate)oxy)hexyloxy)-2,2,6,6-tetrammethyl poperidin (EHT), which contained TEMPO unit and ethyl benzoate unit, was successfully synthesized. POBE was prepared via chain-growth polycondensation using EHT as an initiator, ethyl 4-(octylamino)benzoate (OBE) as a monomer and lithium hexamethyldisilazide (LHMDS) as a base. The block copolymer, POBE-b-PSt, was prepared via nitroxide-mediated polymerization (NMP) using POBE as a macro-TEMPO agent and styrene (St) as a monomer in bulk polymerization. Meanwhile, another block copolymer, POBE-b-PMMA, was prepared by coupling TEMPO unit from POBE with the radical derived from PMMA which was prepared via atom transfer radical polymerization (ATRP) in toluene. The obtainedcopolymers were characterized by GPC and 1H NMR spectroscopy.Synthesis of comb-copolymers via combination of chain-growth polycondensation and LRP. System I: Synthesis of comb-copolymers with polyamide main chain and polystyrene side chain. Ethyl 4-(N-(6-(4-(2,2,6,6-tetramethylpiperidinooxy)oxyl)hexyl)) aminobenzoate (TEAB) was successfully synthesized. PSt with well-defined molecular weight and narrow molecular weight distribution was prepared via NMP using TEAB as a TEMPO agent and St as the monomer. Comb-copolymer was prepared via chain-growth polycondensation using the obtained PSt as a macro-monomer, phenyl 4-nitrobenzoate as an initiator and lithium hexamethyldisilazide (LHMDS) as a base. System II: Synthesis of英文摘要结合可控缩聚和“活性”/可控自由基聚合方法合成嵌段和梳状共聚物comb-copolymers with polystyre