N-苯基-3-氯邻苯二甲酰亚的合成工艺条件优化 毕业论文.doc

N-苯基-3-氯邻苯二甲酰亚胺的合成工艺条件优化 目 录 摘 要........................................................... 1 ABSTRACT....................................................... 1 1文献综述........................................................ 2 1.1引言...................................................... 2 1.2二苯硫醚四酸二酐的性质及用途.............................. 3 1.3二苯硫醚四酸二酐的国内外研究现状........................... 4 1.4 N-苯基-3-氯代邻苯二甲酰亚胺的性质及用途.................... 4 2实验部分........................................................ 5 2.1.主要试剂.................................................. 5 2.2实验仪器.................................................. 5 2.3实验装置.................................................. 6 2.4实验步骤.................................................. 6 2.5分析条件.................................................. 7 3 合成工艺条件优化............................................... 9 3.1原料配比对产物收率的影响.................................. 9 3.2反应时间对产物收率的影响.................................. 10 3.3反应温度对产物收率的影响.................................. 11 3.4溶剂醋酸用量对产物收率的影响............................... 12 4 产物的表征...................................................... 14 4.1 差示扫描量热法（DSC）N-phenthyl-3-Cl-chorophenthalimide was prepared by the reaction of 3-chlorophthalic anhydride with phenthylamine in acetic acid solution. The paper studied the effects of molar ratio of matiral, reaction time, reaction temperature and the volume of solvent on the yield of the product. The product was identified by FTIR, DSC and NMR. The optimal reaction condition was obtained with molar ratio of 3-chlorophthalic dianhydride and phenthylamine1:1.5, reaction temperature 120℃ in 3h with a yield of 96.8%. Keywords 3-chlorophthalic dianhydride, acetic acid, phenthylamine N-phenthyl-3-chlorophthalimide, synthesis 1 文献综述 1.1 引言 20世纪以来，随着航空航天技术的发展，各行各业对耐热的轻质结构材料需求十分迫切，这时，一类主链以芳环和杂环为主要结构单元的结构应运而生。主要以聚苯硫醚、聚醚砜、聚醚酮及聚酰亚胺在性能价格比上最为引人注意目。聚酰亚胺作为很有发展前途的高分子材料已经得到充分的认识，在结构材料和绝缘材料方面的应用正不断扩大。但是，聚酰亚胺在发展了近半个世纪以来仍未成为一个更大的品种的一个原因是其