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Fractal Chaacteristics of Modeled Zoning Patterns in Calcite模拟的分区模式在方解石的分形特征
Fractal Statistics of Modeled
Zoning Patterns in Calcite
Natalia Bryksina1,2 , Norman Halden1 and Sergio Mejia1
1Department of Geological Sciences, University of Manitoba, Canada
2 Institute of Mineralogy and Petrography, Novosibirsk, Russia
bryxinan@cc.umanitoba.ca
1. Introduction
In recent years, the phenomenon of oscillatory zoning has been established in more than 70 rock-forming and accessory minerals having been formed in different geological media [Shore Fowler, 1996]. Observations of oscillatory zoning in solution-grown calcite crystals are reported by Reeder et al. [1990]. In these calcites periodic zonal variations in Mn2+content were not correlated with changes in any bulk solution parameters, and it was interpreted that the oscillatory behavior developed autonomously. Wang and Merino [1992] describe a dynamic model for calcite grown from an aqueous solution containing growth-inhibiting cations such as Mn2+. This model, based on a feedback involving H+ accumulation, surface adsorption, and calcite growth inhibition is able to autonomously produce oscillatory changes of Ca2+ and H2CO3 concentrations adjacent to a calcite growth surface without large-scale changes in bulk water chemistry. After a series of simplifying assumptions this model can be reduced to an autonomous system of two ordinary first-order differential equations with five parameters:
(1)
Here, u and v are scaled concentrations of Ca2+ and H2CO3, respectively, next to the crystal surface; ( is the ratio of diffusivities of Ca2+ and H2CO3; ( is scaled value of rate constant; (1 and (2 are positive constants to adjust the ability of H+ to inhibit calcite growth; and ( is a positive constant; all quantities are dimensionless. A qualitative analysis made by Wang Merino [1992] and Bryxina Sheplev [2001] predicts the existence of numerous oscillatory solutions to the equations describing the system.
In this work we use a computer package MATHEMATICA to integrate the system (1) num
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