水热法制备微纳米结构wo3及其气敏与光电性能的分析-preparation of micro-nano structure wo3 by hydrothermal method and analysis of its gas sensitivity and photoelectric properties.docx

propertiesshowthatWO3nanobrickhasthebestsensitivitytowardsNH3,benzene,acetone,methanolandformaldehyde.Thesamplessynthesizedusing10%CTABassurfactanttakessecondplaceandbignanosheetusing20%CTABassurfactanthastheworstsensitivity.Butbignanosheethaslowestresistance,whichisbeneficialtogas-sensingtesting.Fourthly,three-dimensionalWO3nanowallmicrosphereshavebeensuccessfullysynthesizedthroughchangingtheratiobetweenethanolandwater.Theresultsshowthatonlynanosheetcouldbegainafteraddingwatersolventintoethanolsolvent,indicatingthatethanolplayanimportantroleinmorphologycontrol.Gas-sensingpropertiesshowthatnanowallmicrospherehasbettersensitivitytowardbenzene,acetone,methanolandformaldehydethannanosheet.Moreover,therecoveryrateofnanowallsampleisquickerthannanosheet.UndertheilluminationofUVlight,3DWO3nanowallhasgoodsensitivityandresponseratecomparedtocommercialWO3.Fifthly,WO3nanowirenettedmicrospheresandWO3nanoneedleclustershavebeensuccessfullysynthesizedusingglycolandethanolassolvent.TheresultsshowthatonlyWO3nanowirenettedmicrospherescouldbegainedonlyusingglycolassolvent,whilenanoneedleclusterswouldbepresentwhenaddingethanolsolventinglycolsolvent.Moreover,synthesizedtime,temperature,tungstenamountandF127amountcouldalsoinfluencethemorphology.XRDresultsshowthatallthediffractionpeaksofnanowirenettedmicrospherebeforeannealingcanbeindexedashexagonalWO3(H2O)0.333,whilenanoneedleclusterscanbeindexedastetragonalH0.23WO3.Afterannealing,allthesamplesconvertmonoclonalWO3.Gas-sensingpropertiesshowthatnanoneedleclusterhasbettersensitivitytowardsNH3andbenzenethannanowallsamplesandnanowiremicrospheres.ButnanowallsamplehasbettersensitivitytowardsNO2gasthannanowiremicroshpheresandnanoneedlecluster.Sixthly,Nb5+,Sn4+,In3+andZn2+ionswereusedtoimprovethepropertiesofWO3.TheresultsshowthatallthefourionscanbeimbeddedintoWO3crystallatticeandchangethemorphologyandenergybandofWO3.FESEMshowsthatnanowallisgraduallyevolvedintohomogeneousnanoparticleafterdoping.XRDshowthatcrystallinephaseofWO3changefromγ-WO3toα-WO