双子表面活性剂的合成及理化性质的分析-synthesis of gemini surfactants and analysis of their physical and chemical properties.docxVIP

AbstractGeminisurfactantisanewkindofsurfactantwithtwohydrophilicchainsandtwohydrophobicchains.ExperimentsshowthattheGeminisurfactantsgenerallyhavehighsurfaceactivities,suchasthelowcriticalmicelleconcentration(cmc)andthelowsurfacetension(γcmc).Itwillhavethepotentialapplicationsinthefuture.ThereforetheGeminisurfactantresearchhasbecomeafocusinthechemistry.WesynthesizedaclassofthenewGeminisurfactants.Weuseethylenediamine,diaminopropane,hexamethylenediamineandethylacrylatechlorideasthemainrawmaterialstosynthesizetheGeminisurfactants.ByuseoftheGeminisurfactantsasthemodelcompounds,westudytherelationshipbetweenthestructureandsurfaceactivities.WedeterminethesurfaceactivitiesoftheGeminisurfactantsintheaqueoussolution:thecriticalmicelleconcentration(cmc),criticalmicelleconcentrationofthesurfacetension(γcmc),thesaturationadsorptioncapacity(Γmax),thestandardadsorptionfreeenergy(?G0)andotherphysicalandadchemicalparameters.TheresultsshowthattheGeminisurfactanthydrophobicstructurechangedthesurfaceactivities.WestudiedtheparametersoftheGeminisurfactantsurfaceactivity.ItshowedthattheGeminisurfactanthadthelowsurfacetension,whichwasalsolowerthanthatofthetraditionalsurfactants.ThecmcvalueofGeminisurfactantislowerthanthatofthetraditionalsurfactants.Whenthenumberofcarbonatomsofthelinkgoupincreased,thecriticalmicelleconcentration(cmc)andcriticalmicelleconcentrationofthesurfacetension(γcmc)increasedsuccessively;Whenthenumberofcarbonatomsofhydrophobicchainincreased,thecriticalmicelleconcentration(cmc)andminimumsurfacetension(γcmc)decreasedsuccessively.WemeasuredtheviscoelasticpropertiesoftheGeminisurfactantatthedifferentoperatingfrequencies,dilationalmodulus,elasticandviscousincreasedwithincreasingconcentrationwillbeamaximumvalue,afterreducing.Thephaseangleincreaseswiththeconcentration;Indifferentconcentration,thesurfaceactiveagentdilationalmodulus,elasticwiththeincreaseoffrequency,phaseangleandviscositywiththefrequencyIIincreasing.WedeterminedtheGeminisurfactantsintheflotationperformanceofth