石墨烯聚吡咯基超级电容器电极材料的制备及分析-preparation and analysis of graphene polypyrrole supercapacitor electrode materials.docxVIP

AbstractInthisexperiment,graphenewasusedasabasicconstruction,whichhashighconductivityandlargesurfacearea，todesignSDBSintercalated-reducedgrapheneoxide/polypyrrolenanocompositesviainsitupolymerizationmethod.Thentheternaryorganic–inorganiccomplexofpolypyrrole/manganesetetroxide/graphene(PPy/Mn3O4/graphene)nanocompositewasfirstpreparedbyinsituchemicaloxidationpolymerizationofpyrroleinthehostofinorganicmatrixofMn3O4andgraphene,usingcomplexofmethylorange(MO)/FeCl3wasusedasareactiveself-degradedsoft-template.Themorphologyandmolecularstructureofthecompositewerecharacterizedbyphysicalandchemicalmeans,andthesynthesizedmaterialsforelectricalpropertieswerestudiedassupercapacitorelectrodes.Firstofall,PPy(polypyrrole)/SDBS(sodiumdodecylbenzenesulfonate)intercalatedreducedgrapheneoxide(rGO)nanocomposites(PPy/GSR)werepreparedviainsituoxidativepolymerizationofpyrroleontheSDBSinterposedgraphene.FE-SEM(fieldemissionscanningmicroscopy),TEM(transmittingelectronmicroscopy),UV–vis(ultravioletandvisible)absorptionspectroscopy,FT-IR(Fouriertransforminfrared)spectroscopy,XRD(X-raydiffraction)analyzerandTGA(thermogravimetricanalysis)instrumentwereusedtocharacterizethemorphologyandstructureofthesamples.TheresultsshowedthedisorderedGSR(SDBSorganomodified-rGO)disappearedandrGOexistedintheformofindividualgraphenesheetorstackedlayersinPPymatrix.TherGOservesasasupportmaterialfornano-sizedPPyparticles.Inaddition,CV(cyclicvoltammetry)andEIS(electrochemicalimpedancespectroscopy)techniqueswereusedtomeasuretheelectrochemicalpropertieswithathree-electrodecellmeasurement,andGCD(galvanostaticcharge-discharge)withatwo-electrodecellmeasurement.ThespecificcapacitanceofthePPy/GSRnanocompositeachieved277F/gforthePPy/GSR9:1sampleatcurrentdensityof0.1A/gin1MNa2SO4.Secondly,ternaryorganic–inorganiccomplexofpolypyrrole/manganeseIIItetroxide/graphene(PPy/Mn3O4/graphene)nanocompositewaspreparedbyinsituchemicaloxidationpolymerizationofpyrroleinthehostofinorganicmatrixofMn3O4andgraphene,usingcomplexofmethylorange(MO)/