施氏矿物对水体中asv和crvi同步去除试验分析-experimental analysis of simultaneous removal of asv and crvi from water by scheffer minerals.docxVIP

ABSTRACTArsenic(As)andchromium(Cr)pollutionisalwayspresentsimultaneouslyinacidminedrainage,industrialelectroplatingwastewaterandtheareawhereusingCCA.Agreatthreattohumanhealthandenvironmentmaybecausedbythesetwotoxicandcarcinogenicheavymetals.TheWorldHealthOrganization(WTO)stipulatesthatthecontentsofCr(VI)andAs(V)indrinkingwatermustbenotmorethan50μg/Land10μg/L,respectively.ItisextremelyurgenttoseekeffectiveandeconomicwaysofsimultaneousremovalofCr(VI)andAs(V),soastomeettheincreasinglystringentregulationoftheircontrol.WhenremovingCr(VI),Cr(VI)isalwaysreducedtoCr(III)andthenremovedfromwater.However,thereductionenvironmentwillleadtoAs(V)reductiontoAs(III),whichnotbenefitforsimultaneousAs(V)andCr(VI)removal.Therefore,whensimultaneousremovalofCr(VI)andAs(V),adsorptionandionexchangewithoutredoxprocesswillbemoresuitable.Naturalschwertmanniteexistslargelyinacidminedrainage,anditwouldadsorbedalargeconcentrationofarsenicandchromium.Asakindofenvironmentalmineralmaterials,schwertmanniteissmallenergyconsumption,lowcost,noteasytoproducesecondarypollutionwhenusedtotreatheavymetalpollutionwastewater.Inaddition,ithasstablechemicalproperties,highspecificsurfacearea,andthecharacteristicsofporousparticlesizes,whichareadvantageoustoadsorptionofpollutants.Inthisstudy,wesynthesizedschwertmannitethroughafastandeasychemicalmethod,studytheseparateremovalofCr(VI)andAs(V)onschwertmanniteandpHeffectonthisprocess.WealsoconductedbatchteststostudytheefficiencyofchemicalsynthesisschwertmanniteforsimultaneousAs(V)andCr(VI)removal;theeffectsofcoexistingofSO42-andPO43-onCr(VI)andAs(V)simultaneousremoval;schwertmanniteadsorptionabilitiesafterpretreatmentandrecycling.AndwestudythemechanismofsynthesizedschwertmanniteforsimultaneousAs(V)andCr(VI)removalthroughanalysisoftheinfluenceofpHontheadsorptionprocess,thecorrelationofAs(V)andCr(VI)adsorptioncapacitywiththeamountofdissolvingoutsulfate,andcharacterizationmethodsofSEM-EDS,XPS,STEM-EDS(Mapping)characterizationmethods.Thefollowingconclusionscanbeobtainedthr