炭载pd-fe阴极催化剂制备方法及其电催化性能的分析-preparation method of carbon-supported pd - fe cathode catalyst and analysis of its electrocatalyst performance.docxVIP

wasfoundthattwoformsofFe,alloyingandnon-alloyingFeexistinthePd-Fe/Ccatalyst.Thenon-alloyingFecouldbedissolvedinH2SO4solution,whilethealloyingFecouldnotbedissolved.Thus,thePd-Fe/CcatalystwithonlythealloyingFecouldbeobtainedwiththeacidtreatmentmethod.TheelectrocatalyticactivityofthePd-Fe/CcatalystsbeforeandaftertheacidtreatmentfortheoxygenreductionishigherthanthatofthePd/Ccatalyst,indicatingthatFecoudincreasetheelectrocatalyticperformanceofthePd/Ccatalyst.Inaddition,theelectrocatalyticperformanceofthePd-Fe/CcatalystaftertheacidtreatmentfortheoxygenreductionishigherthanthatofthePd-Fe/Ccatalystbeforetheacidtreatment,illustratingthatonlythealloyingFecouldincreasetheelectrocatalyticperformanceofthePd/Ccatalyst.ItismainlyduetothatthealloyingFecouldincreasetheelectrondensityofPdandthenincreasethecontentofPd0inthecatalyst.Therfore,theelectrocatalyticperformanceofthePd/Ccatalystfortheoxygenreductionwouldbeincreased.3.IthasbeenfirstlystudiedthatthePd-Fe/Ccatalystwaspreparedwiththethermaldecompositonmethodusingthemetal-organiccompounds.ItwasfoundthatthethermaldecompositontemperaturehasthelargeeffectontheelectrocatalyticperformanceofthePd-Fe/Ccatalystsforthetheoxygenreduction.Whenthethermaldecompositontemperatureis300℃,theelectrocatalyticperformanceofthePd-Fe/Ccatalystsforthetheoxygenreductionisbest.Ifthethermaldecompositontemperatureislow,organiccompoundcannotbecompletelydecomposed.However,withtheincreasingofthethermaldecompositontemperature,theaveragesizeofthePd-Feparticlesincreasesgradually,andthentheelectrocatalyticperformanceofthePd-Fe/Ccatalystsforthetheoxygenreductiondecrease.TheeffectoftheatomicratioofPdandFeontheelectrocatalyticperformanceofthePd-Fe/Ccatalystsforthetheoxygenreductionwasfurtherinvestigated.Itwasfoundthatwhentheatomicratiois1:1,theelectrocatalyticperformanceofthePd-Fe/Ccatalystsfortheoxygenreductionmainlyisthemosthighest.Keywords:Directmethanolfuelcell,Complexingreductionmethod,thermaldecomposition,Oxygenreduction,Pd-Fe/Ccatalyst,Acidtreatment学位论文独创性声明本人郑