(Cf-SiCf)SiBCN复合材料的力学与抗热震耐烧蚀性能材料学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 万方数据 万方数据 Abstract SiBCN powers were prepared by mechanical alloying. (Cf-SiCf)/SiBCN composites were prepared by hot-press sintering process. The phase compositions and microstructures of the composites were studied, as well as the affe cts of weak interface layer and addit ives (ZrSiO4) on mechanical properties, thermal shock and ablation resistance. The results show that amorphous SiBCN matrix can be prepared by mechanical alloying method. It is formed by hard aggregates of nano-particles. C or BN coatings on the surface of Cf and SiCf were in preparation of dip and pyrolys is method. The thickness of C coatings were not uniform, and the adhesion phenomenon between fibers was very serious. The thickness of BN coatings was a bit thin but fibers dispersed better. (Cf-SiCf)/SiBCN composite prepared by hot-press sintering were mainly composed of β-SiC, α-SiC and BCN. BCN had a turbostratic and amorphous structure. Fibers in composites without weak interface layers arranged in a certain direction. The composites had a feature of brittle fracture. After introducing weak interface layers, fibers lost its preferred orientation. The fracture form was pseudo plastic fracture. However, density and mechanical properties reduced when introducing weak interface layers. The introduction of additives could significantly improve the performances. Its density, flexural strength, elastic modulus and fracture toughness were 2.58 g/cm3 , 235.3 ± 18.4 MPa, 127.4 ± 1.7 GPa and 5.33 ±0.25 MPa.m1/2, respectively. Debonding and pulling out were main toughening mechanism of carbon fibers, and silicon carbide fibers mainly relied on crack deflection and extend crack propagating path. Flexural strength sharply declined with the increased of thermal shock temperature difference. CSS- Aids composites had the fastest declined speed. The residual strength of composites with weak interface layer declined more slowly. BN coatings had the better effect on im