草甘膦废水的资源化处理-化学工程与技术；应用化学专业论文.docxVIP

I I 摘要 摘 要 随着高毒有机磷农药的淡出，高效、低毒、环境相容性好的农药在我国迅速 发展，其中草甘膦是发展最快，产量最大的品种之一。本论文对亚磷酸二甲酯法 生产草甘膦工艺中产生的草甘膦废水进行了资源化处理研究。 针对不同企业生产工艺的特点，本论文以工业化实施为目标，采用两种方法 对该股废水进行了资源化的实验研究。 （1） 化学沉淀法 在适宜的条件下用钙盐将废水中的草甘膦和亚磷酸沉淀分离，其沉淀物用 Na2CO3 去钙后浓缩，浓缩液中的主要成分是亚磷酸和草甘膦，亚磷酸浓度可达 到 250g/L，草甘膦浓度为 80g/L，亚磷酸是 IDA 法合成草甘膦的主要原料之一。 剩余的滤液用 NaClO 二次氧化处理，可将其中的总磷浓度降至 40mg/L。 （2） 二段浓缩结晶法 对废水进行二段浓缩，浓缩液中草甘膦含量在 7.5~8.0%。在 pH=0.5，温度 30℃条件下，动态结晶 20h 后，析出物中草甘膦含量在 50%以上，回收率在 40% 以上。结晶滤液中各种价态的磷可转化成钙盐，对磷酸钙盐进一步利用，可达到 环境与经济的双重效益。 关键词：草甘膦，资源化，沉淀，浓缩，结晶 II II Abstract Abstract With the high toxic organic phosphorus pesticides out of the market, high efficiency, low toxicity and good environmental compatibility pesticides develop rapidly in China. Glyphosate is one kind of pesticides which are the fastest development and the biggest output. This paper was about the separation research of the glyphosate wastewater. Because of the different technics characters of the different enterprises, two ways were used to research and analyse this wastewater in the paper. chemistry sedimentation In order condition, the glyphosate and phosphorus acid were sedimentated from the wastewater with the calcium. The Ca2+ in the solid was wiped off with Na2CO3, and the liquid was condensed. The concentration of the phosphorus acid in the dissolve was 250g/L, and the concentration of glyphosate was up to 80g/L. The phosphorus acid was one kind of the materials of the IDA reaction. The liquid from sedimentation was oxided with NaClO for twice, and the concentration of the total phosphorus was down to 40mg/L in the last. condensation and crystal The wastewater was condensed for twice, the concentration of glyphosate was 7.5~8.0%. The dissolve was rimed in the optimum conditions, the digestion temperature 30℃, pH=0.5, the faction time 20h. In the solid from the crystal, the concentration of glyphosate was above 50%, and the percent of the callback was above 40%. The residual total phosphorus in the ilquid was translated into the salts with C