反复熔铸对非镍基烤瓷合金化学成分及显微结构的影响-口腔临床医学专业论文.docxVIP

化明显，2 次熔铸的纯钛烤瓷合金晶粒有等轴化倾向，3 次熔铸的纯钛烤瓷合金 出现针刺状的β相金相结构；钯基烤瓷合金的金相结构是奥氏体结构，随着反复 熔铸次数的增加，经过 1 次、2 次、3 次熔铸的钯基烤瓷合金晶粒结构略有长大； 原代金铂烤瓷合金的金相结构是由奥氏体结构组成的单相等轴晶，经过 1 次、2 次、3 次熔铸后金铂烤瓷合金晶粒结构未发生明显改变。（3）经过 1～3 次熔铸 后，纯钛、钯基及金铂烤瓷合金的物相结构未发生明显改变；2 次熔铸的钴铬烤 瓷合金发生面心立方结构 fcc 相→密排六方结构 hcp 相的转变。 结论：真空加氩气保护环境下反复熔铸上述 4 种非镍基烤瓷合金，（1）钴铬 烤瓷合金的化学组分钨、钼元素的化学含量随着熔铸次数的增加逐渐下降，纯钛 烤瓷合金的化学组分含量变化无统计学差异，钯基烤瓷合金的化学组分钯、镓元 素的化学含量随着熔铸次数的增加逐渐下降，金铂烤瓷合金的化学组分含量变化 无统计学差异；（2）4 种非镍基烤瓷合金随着熔铸次数的增加，合金表面的缩松 缩孔逐渐增多、晶粒结构逐渐粗化，其中纯钛烤瓷合金出现α→β相转变；（3） 经过 1～3 次反复熔铸后，钴铬合金发生 fcc→hcp 相的转变，纯钛、钯基、金铂 烤瓷合金未发生相变。 关键词：烤瓷合金,反复熔铸,化学成分,组织微观结构 The Effect of Recasting on Composition and Microstructure of the Non-Nickel-based Ceramic Alloys 【Abstract】 Objective: To study the effects of recasting on Composition and Microstructure of the non-nickel-based ceramic alloys. Methods: The non-nickel-based ceramic alloys were recast for 1-3 times under the circumstance of vacuum compressive casting with argon. Before being recast again, the non-nickel-based ceramic alloys should be treated with “the most appropriate way to treat metal alloys before recast. (1) Detected the four kinds of ceramic alloys chemical composition by energy dispersive spectrometer (EDX);(2) According to GB/T13298-91 standards, respectively, grinding, polishing, etching on the four kinds of ceramic alloy, detected the microstructure of the alloy by a scanning electron microscopy(SEM);(3) Detected the phase structure of the four kinds of ceramic alloy by X-ray diffraction(XRD) Results: (1) After casting 1-3 times, there presented no statistical change on the content of chemical composition of Co-Cr ceramic alloys except the element of Co,W, Mo,Ga. Compared with the first generation samples of Co-Cr ceramic alloys, the second one was statistical increase in the content of Co element, the third one was statistical increase in the content of Ga element, the second and the third ones were statistical decrease in the content of W,Mo element; After casting 1-3 times, there presented no significa