钢表面热浸镀AlZnSi合金镀层防腐蚀技术的研究.docVIP

钢表面热浸镀AlZnSi合金镀层防腐蚀技术的研究 　　摘要： 创新性地采用了热浸镀二次助镀工艺，对常用型钢试样表面进行防腐蚀处理，如镀Zn，镀AlZnSi合金，镀ZnRe及镀AlZnSiRe合金.对热浸镀处理后的型钢试样进行拉伸试验，对其组织形貌进行观察，对其力学性能进行测试.另外，在实验室条件下进行模拟酸雨试验和盐雾试验，对各类镀层的耐腐蚀性能进行研究，并与工业镀Zn件的耐蚀性进行对比研究，进而对其使用寿命进行预测.结果表明：热浸镀工艺对型钢的力学性能无不利影响，两种镀层防腐蚀性能优秀，AlZnSi合金镀层对钢材表面的防腐蚀性能卓越，而AlZnSiRe合金的防腐蚀性能更佳. 　　关键词： 热浸镀； AlZnSiRe合金镀层； 二次助镀； 防腐性能 　　中图分类号： TG 179文献标志码： A 　　Anticorrosion Technology Research for Hotdip AlZnSi 　　Alloy Coating on Steel Surface 　　WANG Wenwen，YAN Biao 　　（School of Material Science and Engineering， University of Tongji， Shanghai 200092， China） 　　Abstract： The supplementary secondary hotdip technology as an innovative technique was used to carry out anticorrosion treatment of the common steel surface，such as galvanizing，hotdip AlZnSi alloy，hotdip ZnRe and hotdip AlZnSiRe alloy.Tensile tests were performed on the hotdip treated specimens，and the microstructure and the mechanical properties of the treated samples were investigated.Moreover，the salt spray test and simulated acid rain test were carried out in laboratory conditions，and anticorrosion performance of the specimens was researched accordingly.Then the comparative analyses were made among different kinds of hotdip specimens and industrial galvanized samples.The estimated lifetime of different kinds of coatings are forecasted by comparative analysis.The result shows that the hotdip technologoy has no negative impact for the mechanical property for steels.All the coatings have positive anticorrsion performance.The performance of AlZnSi coating is excellent，and the AlZnSiRe coating is even better. 　　Keywords： hotdip coating； AlZnSiRe alloy coating； secondardy assistant electroplating； corrosion resistance 　　?峤?镀涂层是一种常用的金属腐蚀防护技术，与电镀、化学镀相比，热浸镀可获得较厚的镀层.较厚的镀层作为防护涂层，其耐腐蚀性能和抗氧化性能较普通钢板有较大的提高.作为镀层产品中的主要代表产品，AlZn合金镀层兼有Zn镀层的阴极保护功能和Al镀层的耐蚀性及抗高温氧化性，性能优异的热浸镀高Al含量AlZn合金镀层日益成为镀层领域的重要研究对象[1].自1967年美国伯利恒公司开发出55%Al43.4%Zn1.6Si%合金[2]（%为质量分数，下同），商业名称Galvalume的镀层产品以来，55%Al体系的镀层产品的需求不断地增加，热浸镀55%AlZnSi合金是一种优良的钢制品涂层保护材料，