磁性聚合物微球制备分析-材料学专业论文.docxVIP

湘潭大学 湘潭大学 2011 届硕士学位论文 II II Abstract The current research involved the preparation of magnetic hollow polymer microspheres and magnetic fluorescent polymer microspheres. The following two aspects were included. The magnetic hollow polymer microspheres were prepared according to a two-step procedure including the preparing of magnetic polymer latex with core-shell structure by soapless emulsion polymerization and a sequential of seeded emulsion polymerization and alkali swelling treatment of the obtained core-shell latex to form the hollow polymer microspheres. The size and size distributions of magnetic polymer microspheres were characterized by dynamic light scattering (DLS), and electron microscopy was used to characterize the morphologies of the particles. Magnetic fluorescent polymer microspheres were prepared by the combination of soapless emulsion polymerization and Click reaction. Firstly, magnetic polymer microspheres were prepared by soap-free emulsion polymerization of methyl methacrylate (MMA) with 2-Azidoethyl Methacrylate (AzEMA) using divinyl benzene (DVB) as cross-linking agent in the presence of bilayer-oleic acid-stabilized aqueous magnetic nanoparticles. Subsequently, fluorescent molecules, methyl 2-(3-oxo-6-(prop-2-ynyloxy)-3H-xanthen-9-yl)benzoate were coupled on the surface of the magnetic polymer microspheres by copper(I)-catalyzed [3+2] azide–alkyne cycloaddition reaction. This resulted in the formation of magnetic fluorescent polymer microspheres. The fluorescence properties of the obtained magnetic fluorescent polymer microspheres as well as the different metal cations fluorescence quenching effects were studied by fluorescence spectroscopy and confocal laser scanning microscope. Electron microscopy was used to characterize the morphologies of the magnetic polymer microspheres. Keywords: Emulsion polymerization; Magnetic polymer microspheres; Click chemistry; Fluorescence quenching PAGE PAGE IV 目 录 摘 要 ······················