富铝煤矸石的烧结性能及其莫来石化研究-材料科学与工程专业论文.docx

万方数据 万方数据 4．以大峪沟煤矸石为原料，添加 40%（w）玉米淀粉为造孔剂，聚乙烯醇 溶液（PVA）为结合剂，经 1500℃保温 3h 烧成后，可制得轻质多孔莫来石原 料，其体积密度和显气孔率分别为 1.19g·cm-3 和 62%。烧成试样中所含物相为莫 来石固溶体（Al4.80Si1.20O9.60）以及刚玉相（Al2O3），且随着烧成温度的升高， 莫来石相的相对含量呈现增大趋势，1500℃时有极大值 73%。莫来石晶体结晶 完好且发育呈∥C 轴、横断面为四边形的柱状，长度为 3~10μm。由于淀粉粒径 小，生成的气孔以微孔为主且分布较为均匀，呈狭长形，尺寸在 1~5μm 左右。 关键词：富铝煤矸石；综合利用；烧结性能；莫来石化 II Abstract The exploitation and utilization of coal play a huge role in the social economy. At the same time, it also has significant negative impact on the environment. More than one billion tons of coal gangue is regarded as a kind of the largest industrial solid waste in China. Its resource-oriented utilization has become the focus of research. In this paper, coal gangue from Henan Dayugou Hongqi Coal Group was used as starting raw material. Analytical techniques such as inductively coupled plasma emission spectrometer (ICP-AES), high-resolution field emission scanning microscope (HR- FESEM+EDS), X-ray diffraction (XRD), simultaneous thermal analyzer and particle size analyzer were introduced to characterize the properties of coal gangue ore and prepared specimens so as to obtain a comprehensive evaluation of coal gangue. Coal gangue mineral was sorted, crushed, sieved and purified followed by sintering at high temperatures. Mullite homogenization material and porous lightweight mullite material were prepared. This work mainly discussed the influence of technological parameters such as particle size, sintering temperature and soaking time on the mullitization of coal gangue, and then applying to the industrial synthesis of mullite raw materials. The significant results were obtained as follows: The classification of coal gangue used in this experiment belongs to aluminum rich coal gangue. The main chemical compositions of coal gangue clinker are Al2O3 (67.33%) and SiO2 (22.05%). The main phases are diaspore (AlOOH) and a small amount of kaolinite and pyrophyllite. Microscopic morphology presents as flake-like under the scanning electron microsc