典型土壤环境下X100管线钢的缝隙腐蚀机理研究-材料科学与工程专业论文.docx

内蒙古 内蒙古科技大学硕士学位论文 III III medium degree of crevice corrosion. Simulation results show that the X100 pipeline steel slit specimen, in yingtan, korla, soil simulation solution under medium, pass into the seam - 1000 MVCS polarization voltage, with the extension of the polarization time of each location in the seam of polarization potential gradient descent trend; Polarization in the same time, the seam to seam at the bottom of the increase of polarization potential gradient certain trend, and with the polarization of the extension of time, the seam to the bottom of the seam less change of polarization potential gradient; X100 pipeline steel simulation crack sample in yingtan, korla, soil simulation solution under medium, with the reduction of seam control potential seam polarization potentials of each location are present within a certain gradient of negative shift phenomenon; When the polarization potential - mvcse mvcse, 1000-1000, each location in the seam polarized electrode are below the critical voltage protection, cathodic protection effect; When the voltage of seam - 850 mvcse, yingtan simulated soil solution under medium, seam deep in the bottom of an under-voltage protection state. Key Words: X100 steel ; Crevice corrosion; Cl- concentration ; Cathodic polarization PAGE PAGE 1 目 录 摘 要 I Abstract II 引 言 1 1 文献综述 2 1.1 X100 管线钢的特点及应用 2 1.1.1 X100管线钢简介 2 1.1.2 X100管线钢合金元素的作用 2 1.1.3 X100管线钢的研究应用 4 1.2 土壤环境下埋地管线钢的腐蚀机理 4 1.2.1我国典型土壤环境 5 1.2.2管线钢土壤环境局部腐蚀类型 5 1.2.3土壤腐蚀的电极过程 6 1.2.4土壤腐蚀的几种常见形式 6 1.3 关于缝隙腐蚀基础理论 7 1.3.1 缝隙腐蚀机理 7 1.3.2 缝隙腐蚀的影响因素 8 1.3.3 缝隙腐蚀研究方法 9 1.3.4 缝隙腐蚀控制措施 10 1.4 选题意义及研究内容 12 1.4.1 选题意义 12 1.4.2 课题研究内容与实验方案 12 2. 实验材料与实验方法 13 2.1 实验材料与腐蚀介质 13 2.1.1 材料化学成分 13 2.1.2 实验试样制备 13 2.2.3 腐蚀介质 14 2.2 实验方法 15 2.2.1 模拟缝隙环境实验装置 15 2.2.2 Ag/AgCl 微型 Cl-离子选择性电极制作 16 2.2.3电化学测试方法 17 2.2.4阴极极化测试方法 17 3 X100 管线钢在酸碱中性土壤的缝隙腐蚀行为 18 3.1 缝隙内不同位置处氯离子浓度分布 18 3.2 缝隙内不同位置处电极电位分布 21 3.3 缝隙内电化学阻抗谱的测定 25 3.4 腐蚀形貌与腐蚀产物分析 28 3.5 本章小结 30