高分子-磁性粒子杂化膜制备与渗透蒸发性能研究-化学工艺专业论文.docxVIP

万方数据 万方数据 magnetic field (the direction of magnetic field lines was perpendicular to the membrane surface), Fe3O4 nanoparticles were aligned in the direction of magnetic field, which constructed channels at the continuous interface region between nanoparticles and polymer, thus facilitating transmembrane water diffusion. Effects of FeCl2?4H2O content and the magnetic filed on membrane pervaporation performance were investigated. When FeCl2?4H2O content was 8 wt.%, the hybrid membrane in the magnetic field possessed the optimized performance with a flux of 1042 g/m2h and a separation factor of 674. The external magnetic filed enhanced the permeation flux with a little sacrifice of separation factor of the hybrid membrane. Carbon nanotubes (CNT) surface-loaded with Fe3O4 (Fe3O4@CNT complex) were blending into SA matrix to prepare hybrid membranes. Fe3O4 loaded at the surface of CNT improved the dispersion of CNT, and one-dimensional CNT in turn facilitated the ordered arrangement of Fe3O4. The introduction of Fe3O4@CNT not only decreased the crystallinity of adjacent SA matrix and favored the production of free-volume cavities, but also constructed the channels for water diffusion and enhanced the rigidity of polymer chain. Effects of Fe3O4@CNT, pristine Fe3O4 and CNT contents on membrane pervaporation performance were investigated. When Fe3O4@CNT content was 2 wt.%, the hybrid membrane acquired the optimized performance with a permeation flux of 2211 g/m2h and a separation factor of 1870. That performance was higher than those of the hybrid membranes incorporated with pristine Fe3O4 or CNT, owing to the synergistic effect of Fe3O4 and CNT. KEY WORDS: Magnetic particle, Hybrid membrane, Interface, Pervaporation, Dehydration of ethanol 目 录 HYPERLINK \l _bookmark0 前 言 ................................................................................................................................................1 HYPERLINK \l _bookmark1 第一章 文献综述...............