介孔金属氧化物催化剂应用于αc时-h键活化反应.docx

上海师范大学硕士学位论文 上海师范大学硕士学位论文 Abstract Abstract The activation of inert C—H bond is one of the most rapidly developing directions in the field of chemistry in recent years．High added organic compounds can be synthesized by inert chemical bond activation from simple organic compounds，which can greatly improve the synthesis efficiency and atomic economy．HoweveL the traditional homogeneous C-H bond activation reaction facing some problems，such as the catalyst is difficult to be recycled，requires complicated and expensive ligands，the reaction condition is harsh(anhydrous and anaerobic)，using additives，dependent toxic flammable organic solvents and heavy metal residues and other issues．The heterogeneous catalyst has natural advantages in this area，which Can provide reference for potential industrial application．From the point of view of green chemistry,we have synthesized functionalized mesoporous metal／oxide catalysts for the coordination environment of metal／oxide and the chemical properties of the surface，which can achieve the purpose of activating the inert(0t-)C-H bond．In this paper,we have studied the palladium-catalyzed indole C2 selective arylation reaction in aqueous medium,as well as Ce02一C catalytic oxidation of benzyl alcohol under alkali system for the elimination mechanism benzaldehyde process 0【-C—H bond．And we have got the following interesting results： (1)A phase·transfer-agent-functionalized ordered mesoporous resin material， which is synthes泣ed by a micelle—templated approach，is used to support a heterogeneous Pd catalyst．The catalyst possesses an interpenetrated inorganic—organic framework．Coordination with highly dispersed Pd nanoparticles creates an electronically rich environment for surface atoms and CaUSeS a distinct enhancement in the stabilization and accessibility of these particles to organic substances in aqueous solution．The ligand—free mesoporous Pd ca