导热增强型聚醚基复合相变材料的制备与性能精细化工专业论文.docxVIP

导热增强型聚醚基复合相变材料的制备与性能Preparation 导热增强型聚醚基复合相变材料的制备与性能 Preparation and Properties of Polyether Based Composite Phase Change Materials with Enhanced Thermal Conductivity Abstract Thermal conductivity enhancement of composite phase change energy storage materials have been prepared by the sol—gel method in this thesis．Inorganic Si02 and PEG with high phase change enthalpy were used as support materials and phase transition component， respectively．The form—stable phase change materials had good phase change property,high thermal conductivity because of addition of various materials，such Ti407、carbon fibre and metal form Ni． Th07／PEG／Si02 form．stable phase change materials were prepared by acid-base sol—gel method and in—situ doping Ti407．ne structure and performance characterization of composite PCMs were studied by SEM、FT-IR，XRD、DSC，TG coefficient of thermal conductivity and thermal conversion test，and heat storage capacity test．Results indicated that it was physical mixture among each material．PEG chains bounded in three dimensional network structure of Si02，on account of amorphous phase transformation performance the composite materials had no leakage phenomenon in the process of phase transition．Because of the addition of Ti407 with excellent performance of thermal conductivity，its coefficient of thermal conductivity improved，the rate of store heat and release heat were accelerated．Ti407 in ultraviolet—visible had strong ability of light absorption and transformation，which can be used for the capture and utilization of ultraviolet—visible high-energy light，which was 45％of the solar radiation energy,SO to improved utilization efficiency of solar energy． When Ti407 content reached 3％in the composite PCMs，the phase transition enthalpy value reached up to 145．0 J／g，coefficient of thermal conductivity was 0．45 W／(m‘K)．When the temperature was below 360℃，composite PCMs had good thermal stability． By acid and alkali catalytic sol-gel method in-situ doping carbon fiber(CF)，