光固化含氟环氧丙烯酸酯树脂的合成及性能研究材料工程专业论文.docxVIP

广东工业大学硕士学位论文树脂在成膜过程中含氟链段没有完全运动迁移到涂膜表面。通过接触角分析表明，PI 广东工业大学硕士学位论文 树脂在成膜过程中含氟链段没有完全运动迁移到涂膜表面。通过接触角分析表明，PI 820的用量对GBF树脂固化膜的接触角有显著的影响，与环氧基团的转化率的变化相 符。而含氟单体的引入提高了光固化膜的疏水疏油性。通过接触角计算得出固化膜的 表面自由能，结果表明光固化膜的表面自由能要大于热固化膜的表面自由能。研究还 发现热处理能促进含氟链段的运动迁移，增大了光固化膜的疏水疏油性。 (3)将GBF树脂、环氧丙烯酸酯树脂(EA)、1,6一己二醇二丙烯酸酯(HDDA)、阳离子 光引发剂PI 820以及自由基光引发剂IGRACURE 184共混得到了自由基一阳离子混杂 光固化涂料，通过实时红外研究了混杂光固化动力学，并研究了混杂光固化膜的表面 性能及热稳定性等。实时红外研究结果表明，混杂体系中环氧基团的转化率随着GBF 树脂含量的增加而升高，而碳碳双键的转化率则先上升后下降，但碳碳双键的聚合反 应仍是主导，两者表现出良好的协同效应。凝胶率测试表明，混杂光固化膜的凝胶率 大于阳离子光固化膜的凝胶率，且随着GBF树脂用量的增加，混杂光固化膜的凝胶率 呈下降趋势。通过接触角及表面自由能分析发现，GBF树脂提高了混杂光固化膜的疏 水疏油性、降低了固化膜的表面自由能，而热处理同样也能增强混杂光固化膜的疏水 疏油性。通过TGA分析发现，混杂光固化膜在450 oC基本分解完全，表现出良好的热 稳定性。此外，随着GBF树脂含量的增加，混杂光固化膜的热稳定性降低。 关键词： 含氟丙烯酸酯； 光固化； 接触角； 表面自由能 万方数据 A A BSTRACT ABSTRACT UV-curing technology has been widely employed in industry as a green and environmental friendly route with the advancement of science and technology．The fluorinated polymer has great prospects in functional coatings due to its low surface energy， excellent thermal stability,aging and chemical resistance，etc．Therefore，the combination of UV-curing technology and fluorinated polymer is of great importance Fluorine—containing acrylate resins are often used as low surface energy coatings．They possess controllable structure，simple preparation and easy usage．In this paper,epoxy functional fluorinated acrylate resins were synthesized vi a solution polymerization which be used in UV-cuing system．Low surface free energy films were obtained by thermal curing，cationic UV-curing and free radical—cationic hybrid UV-curing，respectively． UV-curing kinetics was studied as well．Moreover,the GBF resins were characterized by FT．IR，NMR，DSC and TGA．The cured films were studied by SEM—EDS，contact angle． The main WOrks are as follows (1)In this paper, glycidyl methacrylate(GMA)， butyl acrylate(BA) and dodecafluoroheptyl methacrylate(G04)were used as raw materials，and epoxy functional fluorinated acrylate resins(GBF resins)were obtained via solution