高色度去除率改性活性炭的制备与表征.PDF

第 43 卷第 4 J!j) 浙江工业大学学报 Vo l. 43 No. 4 2015 年 8 月 JOURNAL OF ZHEJIANG UNIVERSITY OF TECHNOLOGY Aug. 2015 高色度去除率改性活性炭的制备与表征 陈红英，张毒，吴超，施晓帆 (浙江r:业大学建筑 [fl! 学院，浙江杭州 310014) 摘要:通过对活性炭进行二次负载改性，以提高其在微波协同活性炭氧化工艺中对活性染料废水的 色皮去除率.主要考察了活性炭改性的活性组分的选择，负载方式的优选以及培烧工艺的优化.结 果表明:二次负载改性活性炭采用先负载住后负载铜的方式为最优方式，其效采优于混合负载效 果;XRD 图谱分析表明分别负载 Mn 和 Cu 两种活性组分可以以 CUz 0 , CuO , Mnz ()3 ， MnOz 等形 式存在于活性炭表面;对于总体和、为 100 mL、质量浓度为 O. 1 g/L 的活性艳红溶液，微波 2 min(微 波功率为 595 W) ，先负载钱后负载铜改性活性炭投加量为 0.03 g/mL ，色皮去除率达到 99%. 关键询:改性活性炭;色度;微波;染料废水 中图分类号:X703. 1 文献标志码:A 文章编号: 1006-4303(2015)04-0460-04 Preparation and characterization on high chroma removal rate of modified activated carbon CHEN Hongying , ZHANG Qian , WU Chao , SHI Xiaofan (College 01 Civil Engineering and Architecture. Zhejiang University 01 Technology , Hangzhou 310014 , China) Abstract: To enhance the color r巳moval rate of the reactive dye wastewater in microwave assisted with modifi巳d activated carbo日， the granular activated carbon was two times modification by loading different active groups. Th巳 main study of th巳 text was that the selection of the modified active group , the selection of load mode and the optimization of roasting process. The results show that the optimum way for modifying the activated carbon was that first step was loading the manganese and the second step was loading the copper , which is better than the way of two active groups mixed loaded on the carbon. The XRD spectrum analysis indicates that there is Cuz 0 , CuO ,MnZ 03 and MnOz respectively in the surfac巳 of activ