介孔TiO2的制备、改性及用于光催化降解反应-物理化学专业论文.docxVIP

曲阜师范大学硕士学位论文 曲阜师范大学硕士学位论文 曲阜师范大学硕士学位论文 曲阜师范大学硕士学位论文 PAGE IV PAGE IV 万方数据 万方数据 万方数据 Abstract This paper introduced the preparation o f mesoporous CdS-TiO2 and Ag-AgCl- TiO2 composites and the photocatalytic degradation of organic pollutants by these composites under visible light. In the first part, the TiO2 was prepared by hydrothermal method with Ti(SO4)2 as titanium source, CTAB as the template. And then the semiconductor CdS was loaded on the TiO2 to form CdS-mesoporous TiO2 composite photocatalyst. The dispersion state of CdS was controlled by different loading methods with controlled amounts of CdS. XRD, TEM were used to characterize the composite catalysts, and their photocatalytic activity was tested by photocatalytic degradation of Rhodamine-B solution under visible light. The results showed that high dispersed CdO can be controlled by adding citric acid, and then high dispersed CdS- TiO2 was obtained. The photocatalytic degradation of Rhodamine-B solution was used as a probe reaction, and the degradation rate can reach more than 98% with high dispersed CdS-TiO2 as catalyst. Therefore, the loading of CdS can not only broaden the spectral response of TiO2, but also help the effective separation of the light-generated electrons-holes of the composite catalyst which greatly improvedg its photocatalytic activity. In the second part, Ag-AgCl- TiO2 and Ag-AgBr- TiO2 composite with plasmon resonance effect were prepared by chemical deposition-photoreduction method with mesoporous TiO2 as carrier. The amounts of AgCl, AgBr and photoreducting time were controlled, and then two series of Ag-AgCl- TiO2 and Ag-AgBr- TiO2 composite photocatalyst was prepared. Their photocatalytic activity was tested by photocatalytic degradation of MO solution and Rhodamine-B solution under visible light. The results showed that the compounding of Ag-AgCl and Ag-AgBr on the mesoporous TiO2 can also broaden the spectral response of TiO2, and help the separation of the light- generat