基于含醚键烷基季铵阳离子的聚合物离子液体合成与表征-有机化学专业论文.docxVIP

华 华 中 科 技 大 学 硕 士 学 位 论 文 PAGE 10 PAGE 10 ABSTRACT Polymeric ionic liquids are the polymer which is polymerized by ionic liquid monomers. As novel polymer electrolyte, polymeric ionic liquids are prepared by complementation of merits and demerits of ionic liquids and polymer electrolyte. Polymeric ionic liquids has inherited some properties of ionic liquids, such as nonvolatile, nonflammable, slightly toxicity, good chemical stability, and wider electrochemical window, and also inherited many advantages of polymer electrolytes, including lightweight, leak proof, no environment hazards, simple structure, safe and reliable, etc. Such inherit characteristics have received great attention from the scientists, and, it is considered to be new material to replace liquid electrolyte, resolve the safety problem of ionic liquid electrolytes and low electrical conductivity of conventional polymers electrolytes. In this thesis, a dozen kinds of novel ionic liquids consisting of different number ether bonds were designed and synthesized, and, with investigation of such ionic liquids as the raw material, we had prepared two kinds of polymeric ionic liquids, which were the polyanionic ionic liquids and polycationic ionic liquids respectively. The chemical structures of ionic liquids were confirmed by 1HNMR, 19FNMR, and IR. And, the physical properties and electrochemical properties of such ionic liquids was characterized and discussed. Then, the paper emphatically discussed properties of polymeric ionic liquids which has multiple ether bonds structure and mixed with different concentration lithium salts (electrical conductivity, glass temperature, the transference number of lithium ion, etc). All polymeric ionic liquids in this thesis, the polycationic ionic liquids of multiple ether bonds was characterized by low glass transition temperature（-47 oC）and high ionic conductivity (when 25 oC, the high ionic conductivity is 5.68× 10?5 S/cm). In addition, the result of the thermal s