胶质气体泡沫的制备及其驱油性能的研究-化学工程与技术专业论文.docxVIP

摘 摘 要 胶质气体泡沫(CGA)具有独特的结构和性质，在泡沫流体驱油方面有较好的应用 前景。传统泡沫流体驱油在矿场运用中遇到注入压力高、沥青质等有机固相沉积引发相 分离堵塞驱油孔道等诸多问题，故开发一种新型的驱油泡沫十分重要。本研究在CGA 中引入改性剂，对CGA起泡体系进行筛选，并对CGA的制备条件进行优化分析。以 Mereyl6原油和风城模拟油为基础油对CGA进行泡沫驱的实验室研究，测量最优浓度 下不同CGA体系的油水界面张力，通过光学显微镜等对其结构和性质进行分析，考察 注入压力、采收率及驱出原油中沥青质的变化。 实验进行了加入改性剂条件下单一及复配CGA起泡体系的筛选以及含改性剂和空 白体系下制备条件的优化分析，主要考察了起泡剂种类及浓度、稳泡剂浓度、搅拌速率、 搅拌时间、成泡温度、矿化度等对CGA泡沫量及稳定性的影响，研究发现：在改性剂 (GXJ-II)浓度0．19／L、搅拌速率8000印m、搅拌时间3min条件下OP．10(39／L)与SDS (19／L)复配，制备的CGA泡沫量590mUl00mL，半衰期420s，同样条件下，SYHSY (39／L)与SDS(29／L)复配制备的CGA的泡沫量580mL／100mL，半衰期265s；采用光 学显微镜观察泡沫形状发现其多为多层透明球状，且有液晶相存在。 在最佳条件下制备CGA用于实验室驱油，研究表明：单一驱替Mereyl6原油时，改 性CGA比空白CGA的注入压力降低约20％～40％，采收率由水驱的41．6％、空白CGA驱 的56．6％提高到改性CGA驱的62．8％；在模拟岩心中梯度驱替Mereyl6原油时，改性CGA 注入压力明显降低，在水驱、空白CGA驱基础上提高了20．9％的采收率，驱出原油中沥 青质含量较水驱、空白CGA驱增加了26．8％、34．9％，界面张力由3．20mN·m‘1降低到 2．78mN·m．1；梯度驱替凤城模拟油时，改性胶质气体泡沫驱在水驱、空白胶质气体泡沫 驱基础上提高了11．1％的采收率。本研究建立的改性CGA新型驱油泡沫流体具有重要的 理论意义和工业利用前景。 关键词：泡沫驱，胶质气体泡沫，采收率，注入压力，界面张力 Preparation Preparation of Colloidal Gas Aphron and its properties study on oil displacement Wang zhan(Chemical Engineering and Technology) Directed by Associate professor Guo Ai—Jun Senior Engineer Mu Bao-quan Abstract Colloidal Gas Aphron(CGA)has a great potential in foam flooding，because of its special structure and nature．There are some problems in traditional foam—drive process such as high injection pressure，asphaltene and other organic matter depositing in the drive hole，SO it is necessary to develop a new driving foam．At first,we focused on adding modifier to CGA and selecting foam system of CGA in this study，optimization analysis of conditions to prepare CGA Was then carried on．Merey 1 6 Crude oil and Feng-cheng simulated oil were taken as base oil to study on CGA foam flooding，we measured the interfacial tension of different CGA system under optimal concentrations，discussed structure and stability of CGA with the help of optical microscopy，injection pressure，recovery rate and the changes in asphaltene were also measured． In this experiment，we did rese