焦磷酸钾和鼠李糖、鼠李糖脂淋洗修复铜污染土壤的研究-环境科学与工程专业论文.docxVIP

广东工业大学硕士学位论文鼠李糖脂淋洗主要以酸提取态为主。 广东工业大学硕士学位论文 鼠李糖脂淋洗主要以酸提取态为主。 (4)实验浓度范围内，焦磷酸钾和鼠李糖、鼠李糖脂对铜的复合淋洗率贡献值 E0，说明焦磷酸钾联合鼠李糖、鼠李糖脂淋洗对铜的解吸为协同增溶作用，并且 随着鼠李糖、鼠李糖脂浓度的增大，协同作用先增强后减弱。 (5)与单独使用鼠李糖、鼠李糖脂淋洗相比，复合淋洗使用较少的淋洗剂用量 可以达到相近或更好的淋洗效果，焦磷酸钾对鼠李糖脂的淋洗效果提升更明显。混 合淋洗液在鼠李糖质量浓度2％、鼠李糖脂质量浓度4％时基本达到平衡，此时对铜 的淋洗率分别为57 25％和45．02％。鼠李糖复合淋洗液去除的Cu主要以酸提取态和 可还原态为主，两种形态与淋洗前相比分别减小了35．49％和20．46％。鼠李糖脂复 合淋洗液去除的铜主要以酸提取态为主，可还原态部分减少，两种形态分别降低了 31．70％和11．60％。相对于鼠李糖和鼠李糖脂单独淋洗，焦磷酸钾促进鼠李糖和鼠李 糖脂洗脱的铜主要为酸提取态和可还原态。 使用环境友好的螯合剂焦磷酸钾联合鼠李糖、鼠李糖脂对污染土壤中铜的淋洗 修复取得较好效果，该技术具有理论和实际可行性，应用前景广阔。 关键词：重金属；土壤淋洗；焦磷酸钾；鼠李糖；鼠李糖脂 万方数据 AbstractAbstract Abstract Abstract With the properties of poor mobility and bioaccumulation，excess heavy metals in soil not only inhibit the growth of crop and destruct soil microbial communities，but also threat the human health badly through food chain Soil washing is an important technique in soil remediation with thorough restoration and short operation cycle both for heavy metals and organic matter The Cu contaminated soil was researched in this study，with the method of shaking extraction．The copper removal was analyzed after the extraction by potassium pyrophosphate，rhamnose and rhamnolipid，regard of leaching time，the chelant concentration，eluent pH and other important conditions．At the same time，the changes of copper distribution before and after leaching were studied．Compared to the removal of copper with pyrophosphate alone，the combination of chelants was processed too．The results of this study were shown as follows (1)With the extension of reaction time，the copper removal increased，and reached 20．99％when the leaching time was 24h，followed by essentially flat．While the pH of pyrophosphate was 7．0，leaching of copper is maximized for 34．49％Considering the costs and copper removal，a molar ratio of 7：1 as the optimal concentration of leaching experiments was selected；BCR sequential extraction before and after soil washing indicated that potassium pyrophosphate mainly remove copper of acid-extractable and had little eff