结晶器铜板表面超音速等离子喷涂制备氧化锆涂层的基础分析-钢铁冶金专业论文.docxVIP

西安建筑科技大学硕士论文 西安建筑科技大学硕士论文 Fundamental Study on Supersonic Plasma Sprayed Zirconia Coatings on Copper Plate for Continuous Casting Mold Speciality：Ferrous metallurgy Name ：Jian Zhang Instructor ：Prof. Jun Yang ABSTRACT In the processing of continuous casting of steel, the mold is described as the heart of continuous casting machine. Hence the performance and service lifespan of mold are crucial factors which influence the surface quality, cost of casting slab and efficiency of production. Previous researches and practical applications revealed that thermal cracks and thermal deformation at the meniscus and severe wear at the bottom of the mould are the main failure modes of the mold. In addition, other factors such as high-temperature oxidation, chemical corrosion caused by mold flux, cavitation erosion and scratch caused by width adjusting on-line also contribute to the failure of mold. According to the relatively statistics, the annual expense for replacement and maintenance of mold was about 2 billion Yuan in the main top steel making enterprises in China, while the primary mode to failure of mold is wear. Therefore, research and development of the long-lifespan mold has become the key factor to improve surface quality of slab, reduce cost of semis and promote the equipment level of continuous casting machine. Plasma spray is a complex process which heats and ionizes the introduced gases by non-transferred arc generated between anode and cathode to melt sprayed materials into molten droplets, and to inject the droplets by plasma jet at a particular velocity to impact and adhere to the target substrate, therefore leading to formation of coatings. The sprayed coatings can endow the inner surface of the mould with wear resistance, anti-chemical corrosion, high-temperature oxidation resistance and electrical and thermal insulation, radiation-proof, so as one of the most widely used surface strengthening and modification technologies, plasma spraying has been successfu