含钠及含铵废水的资源化利用研究.pdf

Abstract Abstract The process of production in projects such as coal chemical industry and industrial desulfurization will produce large amounts of salty liquid wastes. In wastewater treatment stage, many areas only make strict rules on organic wastewater discharge standards, while there is no clear limit to saline wastewater emission, and it is usually discharged as clean water. With environmental protection consciousness gradually strengthen, in order to save water resources and reduce environmental pollution, most areas requires enterprises to collect and classify wastewater to maximize the recycling, and some restricted by environment even demand no wastewater discharge to achieve zero liquid discharge. However, concentrated saline wastewater processing has been the key issue of restricting ZLD program. Two practical problems for industrial production processes are studied: The first one is concentrated saline wastewater produced by coal-based olefin production process from coal chemical industry, and its main ingredients are sodium sulfate and sodium nitrate. If using evaporation crystallization method to dispose concentrated liquids, a mixture of sodium sulfate and sodium nitrate crystals will be generated largely, and if not handled properly, it may cause secondary pollution under the effect of rainwater leaching; The second is a large amount of ammonium sulfate and ammonium sulfite mixture produced by ammon