硅基电缆式电极锂电性能及柔性平板纤维超级电容器件研究-光电信息工程专业论文.docxVIP

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 Abstract Along with the discovery of Microcosm, the technology go into a new chapter, and the development of nanotechnology promote the related science. The nano-materials science which combines the nanotechnology and material science, have got more and more attention. Popularity of mobile digital products and the Mobile Internet Era and the Electric Car Era make higher requirements of the energy storage devices. Lithium ion secondary devices and Super-capacitors have attracted earnest attention. Finding better energy storage materials and designing more suitable structure for storage devices are critical to get a breakthrough. Since the potential use in weaving devices, wearable digital products and flexible display devices, flexible energy storage devices have become very promising research direction. In this article, we study the Si-based new Cable-type anode and flexible, planar-integrated, all-solid-state fiber super-capacitor, the main contents include the following aspects： The core-shell Si@SiO2 nanowires are synthesized on cabon cloth, through chemical vapor deposition(CVD), and the nanowires wrap around the fibers, forming a new type of silicon-based Cable-type anode. The as-fabricated anodes directly are used for Lithium ion battery package and tests. Based on the anodes, the half-cells exhibit a high capacity (2247 m Ah g-1, on the current density of 800 m A/g), good rate capacity and excellent cycle performance (only 8 % capacity loss in average per 100 cycles, for the hole 1000 cycles on the current density of 8 A/g ). The full-cells based on the anodes also show excellent storage performance, and the full-cells can lighten different colors LED easily, demonstrating the potential practical performance. The ZnCo2O4 nanowire arrays/Carbon fibers composite electrodes are arranged in insert-finger type on PET by silver, forming a new flexible, planar-integrated, all-solid-state fiber super-capac