锅炉水冷壁高温腐蚀特性试验研究-工程热物理专业论文.docxVIP

浙江大学硕士学位论文1 浙江大学硕士学位论文 1 s3 抵要 7809 锅炉水冷壁高温腐蚀造成水冷壁管爆漏，迫使锅炉停机，严重影响了电厂运行 的安全性和经济性，对整个电网的安全生产和调度也造成了严重的后果。因此，近 年来，人们对锅炉水冷壁高温腐蚀问题给予了很多关注，不断的深入研究和解决高 温腐蚀问题。 但是，目前人们对高温腐蚀的研究局限于工程实践的研究，只能根据水冷壁管 的腐蚀产物来作出判断，而对其腐蚀机理以及反应过程缺乏进一步深入的研究。本 文则从实验室出发，在实验室模仿锅炉水冷壁的温度条件和炉膛气氛条件，采用锅 炉水冷壁用钢(20G作为试样材质，尽可能接近锅炉水冷壁的实际工作条件以达 到模仿的效果。并对腐蚀产物进行X．RD衍射分析，对腐蚀增重曲线进行转化，利 用热分析动力学的分析方法对反应机理作出判断，从理论上研究锅炉水冷壁高温腐 蚀机理。这种研究方法具有一定的新意和创新，从方法上讲，丰富和完善了研究手 段；从内容上讲，也较为新颖和充实。 本支对锅炉水冷壁高温腐蚀有关机理、影响因素以及预防措施作了详尽的论 述，并结合工程实际，详细介绍多切圆燃烧技术以及变异周界风技术，从实践角度 介绍多切圆燃烧技术在解决锅炉水冷壁高温腐蚀中的应用。从冷态空气动力场试 验、热态效率试验和实际运行方面出发，验证此项技术在解决锅炉水冷壁高温腐蚀 以及提高锅炉热效率等方面的可行性。 关键词： 锅炉水冷壁高温腐蚀实验室研究热分析动力学 多切圆燃烧技术 工程应用 浙江大学硕士学位论文Abstract 浙江大学硕士学位论文 Abstract The water wall tubes were leaked by the hi曲temperature corrosions，which put the boiler units shut down and made the safety and economy operation of the power plants effected severely，which also made the safety generation and dispatch of the all power network effected severely．Thereby，more and more attentions and researching were given on the problem of the high temperature corrosion of the water wall tubes of the boiler recently． However，researching of the high temperature corrosion is limited in engineering now，only judged by the corrosion products of the water wall tubes，more in—depth researching is lack about the corrosion mechanism and the course of reaction But the paper set out form the Lab，the conditions of the temperature of the water wall tubes and the ambience of the fumace is imitated in Lab，the material of sample is adopted by the steel of the water wall tubes of the boiler，which made the test conditions approach tO the fact work conditions ofthe water wall tubes ofthe boiler and made the imitation accurate The analysis ofX—RD ofthe corrosion products is adopted；the curves ofadd weightiness of corrosion is translated into the thermal dynamic curves，so we can judge the corrosion mechanism by the thermal analysis．The method is fresh and innovation，which made the means of researching and the content en