三元乙丙橡胶及超细碳酸钙增韧聚苯乙烯-材料学专业论文.docxVIP

浙江火学硕十学位论文ABSTRACT 浙江火学硕十学位论文 ABSTRACT Since Ostromislensky applied the first patent on the toughening of Polystyrene in 1 927 and now Chemical Company exploited the continuum producing technique of high impact polystyrene in 1 952，it has been an important task to obtain polystyrene alloys with good integrate properties by modification． The effect of toughening agent，Ethylene-Propylene—Diene terpolymer(EPDM)on the phase structure and mechanical properties of polystyrene(PS)was studied．Styrene- butadiene-styrene(SBS)was used as the compatibilizer．The notched charpy impact strength reaches to a maximum value of 26．3 kJ／m2 at the composition of PS／EPDM／SBS=100／20／10．20 folds comparing to 1．27 kJ／m2 ofpure PS．Investigating the morphologies of the blend by scanning electron microscope(SEM)and transmission electron microscopy(TEM)，we concluded that the increment of the mechanical properties is mainly due to the changes of EPDM phase structure that changed from irregular to spherical，until to interlocked morphology,Monitoring by butanone extraction and FTIR analysis，it is found that there is a graft reaction between PS and EPDM during compounding，it also reveals that the compatibility is promoted by the addition of SBS． Through dynamic rheologic analysis，it is found that there is strong interaction between the components among the systems．With the increment of EPDM content，the interaction is impoved；the modulus is also improved，while the loss factor is decreased． At the salne time，melt blending attalns the composites of Polystyrene(PS)and CaC03 with different radium and different content．The impact strength of the composites are 60～80 percent higher than pure PS．Glass transition temperature(疋)are also increased． The PS／llano-CaC03(1 00／2)composite has the highest impact strength and疋．Results of specific volume analysis and electron microscopic observation of different composites reveal that the free space of the composites decreases with addition of llano-CaC03， inferring