三元乙丙橡胶弹性体增韧改性聚丙烯-化学工程专业论文.docxVIP

游找大学预圭学位论文摘要 游找大学预圭学位论文 摘要 聚丙烯是三种主耍的通用塑料之一，但是由于其低温脆性限制了聚丙烯的更 广泛戆疲震。弹牲体戆共湿改整爨聚嚣爆增韧瓣霍要途径之一。 分别采用茂金属f建化聚合所得的三元乙丙橡胶(mEPDM)和传统Z-N催化 剂聚合所得的三元乙丙橡胶(EPDM)，对聚丙烯(PP)进行了共混改性研究。 竣诗歪交实验方法寒骚究燕王工艺，确定滋较往戆共瀑王艺条磐，奁鼗瑟礁 上研究备工艺条件对凝混物力学性能的影响。实验表明，弹性体增韧PP较优的 工艺条件为：共混时问9分钟，螺杆转速120转／min，加工温度180度。共混物 缝毙慰麴工漫度豹依赖疆不大。嚣蘧着察耪转速懑大秘共霭辩蠢豹延长，荚混纺 的抗冲诲强度有一个最大值，即对于共混加工存在最佳的螺杆转速和共混时间。 考察了弹性体质嫩百分含量的变化对共混物抗冲、拉伸和热变形温度等机械 耱瑾戆貔戆影薅，苏及荚滢穆影态器结鑫瞧熬。与PP／EPDM共滢憨程滋， PP／mEPDM共混物的脆韧转变临界橡胶含量低、增韧幅度犬、断裂伸长率明显 提高。提出了脆韧转变区间的概念，发现PP／mEPDM共混物的脆韧转变区间远 毒予p滟PDM共藏躲。蕤橡获禽豢戆碧热，PP／mEPDM稻PP／EPDM荚溅物静 拉伸强度和弹性模量均单调下降，但PP／EPDM藏混物的下降幅度更大。电镜和 结晶性能研究表明，PP与mEPDM的相容性更好。 在爨验基疆上，硪究了橡蔽禚狡径及冀势带对于弹往髂增秘效果戆影响，发 现临界撼体层厚度的概念同样适用于PP／mEPDM，而且PPImEPDM的临界撼体 层厚度鼹PP／EPDM的2．18倍，发生脆韧转变时的弹性体含量仅15％，丽 PP／EPDM麓隽3鹈《。 关键词：聚丙烯 弹性体 茂金属三元乙丙橡胶 共混 增觏 脆韧转交 浙江大学硕士学位论文ABSTRACT 浙江大学硕士学位论文 ABSTRACT The polypropylene(PP)is one of three kinds of main general plastics．However， the poor impact properties at low temperature limit some of its application．In order to achieve improved properties，impact modifiers have been added to PP．Among the elastomers used，ethylene—propylene—diene terpolymer(EPDM)is the most widely employed． Two types of EPDMs which is synthesized by metallocene catalyst(mEPDM) and by conventional Ziegler-Natta catalyst(EPDM)were used to toughen PP． Process parameters were investigated by means of orthogonality experiment method to abtain optimum mixing conditions．The effects of process conditions on mechanical properties ofblends were discussed．A rotor speed of 120rpm，temperature of 1804C and mixing time of 9rain were considered the ormmam mixing condhions． With the increase of mixing time and rotor speed the impact strength of blends increases first,but at long time and high speed a decrease in impact strength was observed． The effect of mass fraction of elastomers on the properties such as the impact strength，the tensile strength，crystallization performance and Vicat softening point of the PP／elastomers blends Was investigated．The results showed that compared with