磷铝酸盐硅酸盐复合水泥耐久性研究-材料学专业论文.docx

磷铠艘盐-辟睦盐复台水泥耐久性研究分别提高22．6％、17．4‰抗压强度在3d、28d强度分别提高24．6％、10．2％，表现出 磷铠艘盐-辟睦盐复台水泥耐久性研究 分别提高22．6％、17．4‰抗压强度在3d、28d强度分别提高24．6％、10．2％，表现出 良好的抗冻性。 磷铝酸盐一硅酸盐复合水泥浆体不论在抗水渗透还是抗氯离子渗透，都表现出优 于相应硅酸盐水泥浆体的性能。在恒压1．5MPa下，复合水泥砂浆渗水时间较相应硅酸 盐水泥砂浆的滞后了3．5～4．O小时：从28d到90d，复合水泥和PC浆体中氯离子扩 散系数分别下降59～66％和42％．到90d，复合水泥浆体对氯离子的抗渗透能力比PC 强1．6～2．0倍。 较高的水化速率和水化程度，使浆体能尽早地建立起抵御冻融的水化产物结构体 系，从而呈现出较好的耐负温和冻融的行为。 从水化产物C—S．H分子基团结构层次揭示了由于链层状结构的凝胶中聚合[Si041 多面体的解聚因磷铝酸盐熟料与硅酸盐熟料复合而受到遏制，是磷铝酸盐一硅酸盐 复合水泥材质提高，耐久性得到改善的内在原因。 关键词：复合水泥；磷铝酸盐水泥；硅酸赫水泥；力学性能；抗海水侵蚀；抗硫酸镁 侵蚀；冻融循环；抗冻性；抗渗性；耐久性机理 竺塑查兰竺!兰竺篁兰ABSTRACT 竺塑查兰竺!兰竺篁兰 ABSTRACT The durability and mechanical propenies of composite cemellt made with phosphoaluminate—Ponland cement clinkers haVe been studies in this paper The pastes of composite cement haVe been stLIdied by researclling jn composjte cement seawater elosion， magnesium sLIlf乱e erosion，freezing and thawing cycle，the mechanics of negative temperature performance and stress—strain behavjouL and testing of composite cenlellt resistance to water perrueabiJity and resistance to chlorine ion permeability．The technique of X。ray difhactjon，Infbred spectrophotometery，Scalllling electron microscope and NLlcleus IⅥagnetism research haVe been Llsed to analyze the phase const“uents， microstructure and morphology of the composite cenlent 11ardened．This paper discLIsses the reason ofthe mechanism of impmving durabiljty Through the XRD analysis，the composite cement has the good abjIity of resistance to chemical corrosion than Pc，because the phosphoaluminate cement has the good ability of resistance to seawater corrosion and magnesium sulf甜e soIution corrosion，mixing the phosphoaluminate cement into the PC cement，the content of hydration Ca(OH)2 is dcreased in composite cement，thus the content of C3A·CaCl2·10H20、ettringite were much smaller t11an t11at of PC， the C-S—H gel at 1429～1484cm“decomposed much smalIerthan that ofPC，t}1rou曲NMR analysis，the peak of[Si04] at一79．19～一92．44ppm in PC pastes was obVjous smaller lhall that of composite