两亲性多嵌段聚合物的合成-高分子化学与物理专业论文.docxVIP

j．f江大学硬士学位论文Abstract j．f江大学硬士学位论文 Abstract The synthesis and properties ofblock copolymers is always the atWdgtive topic in polymer synthesis．h this thesis,the amphiphilic multiblock copolymers of确rrene and 4-vinylpyridine have been prepared in the讲髑撇of 4，7-diphenyl- 【l，3]dithiolane-2-thione(DPDTT)and the control 0n the block number of multiblock copolymer has been investigated Homopolymerization of styrene and 4-vinylpyridine were carried out in the presellce ofDPDTT as RAFT agent．The polymers containing various trithiocarbonate groups per chain were prepared．The amphiphilic multiblock copolymers (P4VP-b-PS-b-P4VP)．and伊S-b-P4VP-b-PS)．were synthesized via copolymedzation of蚰jrcne or 4-vinylpyridine by using obtained homopolymers as macro-RAFT agent． The polymerization process shows typical characteristics of livimg radical polymerization．Although the molecular weight distribution ofwhole polymer is broad, the molecular weight distribution ofthe block is nalTow． In addition,the kinetics of Styrene polymerization initiated by atom transfer radiacal polymerization(ATRP)in the presence ofDPDTr and the effects ofDPDTT concentration on styrene polymerization were also studied．The variation ofmolecular weight and the block number wim the monomer conversion Was studied for styrene polymerization initiated by 1-PEBr／cllB胛MDEl’A in the presence of DPDTT．The ring-opening polymerization of DPDTT Was controlled by atom transfer radiacal， and the block number of polymer kept constant throughout the whole polymerization process．The molecular weight ofboth polymer and the blocks are well controlled and close to predicted molecular weight when the concentration of DPDTT Was low ([DPDTT]／[I-PEBr]=5)．When the concentration of DPDTT was higll ([DPDTr]／[1-PEBr]=Io)，the molecular weight of polymer Was different from the calculated one based on ATRP,but the molecular weight ofthe blocks still fitted well 诵tll the theoretic values．The molecular weight distributions of polymer are around 2