锂离子电池正极材料V6O13的合成、掺杂及其电化学性能研究-材料科学与工程专业论文.docxVIP

万方数据 万方数据 摘要 因为钒氧化物 V6O13 具有比容量高，放电电压高，且钒的资源丰富，制备所需原料 价格低廉等优点，成为了非常具有发展前景的一种锂离子电池正极材料。但因其化合价 不够稳定，制备相对困难，且结构稳定性较差，也制约了其在锂离子电池领域的发展。 本文使用草酸氧钒溶液和过氧化氢为原料，通过水热法，比对不同配比和煅烧温度 等条件对其物相的影响，成功制备了具有花状结构的 V6O13。通过使用 SEM 分析，比较 了通过不同的干燥方法以及不同的反应温度和反应时间所制备的前驱体的形貌特征，并 提出了这种花状结构的生长模型。同时通过电化学性能测试发现，这种具有这种花状形 貌的 V6O13，因为其“花瓣”之间有大量的空间，可以应对循环过程中产生的膨胀，这 样的结构有利于循环性能的提高。 为了提高花状 V6O13 的电化学性能，我们在合成过程中使用 Cr3+对其进行了掺杂改 性，并通过 XPS 测试，分析了不同量的掺杂后，Cr 和 V 之间的化合价变化。通过 SEM 分析，比较了不同掺杂量对前驱体形貌的影响。同时对其进行电化学性能测试后，发现 随着 Cr3+的掺入，V6O13 的放电容量有明显的增长，通过对 XRD 图谱精修后，发现 Cr3+ 的掺入能够改变 V6O13 的晶格常数使得晶胞体积发生变化。最后通过循环伏安测试，认 为 Cr3+的掺杂能够改变 Li 离子嵌入/脱出 V6O13 的行为 关键词： 锂离子电池，正极材料，花状 V6O13，生长机理，Cr 掺杂 I Abstract Because of the high soecific capacity, high discharge voltage, rich in resource and cheap, more and more researchers regard the vanadium oxide V6O13 as a new generation Li-ion cathode material with vast potential for future development. But its valence of Vanadium is range from +4 to +5, the synthesis is difficult, at the same time, the unsteadily structure become the obstruction for developing in Li-ion battery. In this paper, we prepared V6O13 with flower-like structures via a hydrothemal method. And we compare the effects of different formula and temperature during the process of synthesis.The microstructures of prepared samples were characterized by SEM and we compare the influences on morphology of different dry method and different reaction time and different reaction temperature.According to result The formation mechanism of this flower-like structure has been analyzed.And this flower-like V6O13 showing a better cycle performance due to there is large void space between petals against expansion resulted from insertion of Li ions,and this structure is beneficial during the cycles. In order to improve the electrochemical performance of flower-like V6O13, we doped Cr3+ during the process of synthesis of V6O13 by hydrothermal. The valence of Cr and V were characterized by XPS, and we discussed the morphology changes of