栲胶脱硫法与改良ADA脱硫法的比较-.docVIP

第37卷第4期 2008年4月 应　用　化　工 App lied Che m ical I ndustry Vol .37No .4Ap r .2008 收稿日期:2008202225 基金项目:山西省科技攻关项目(2007032039 作者简介:高艳娥(1981-,女,山西临县人,太原理工大学在读硕士研究生,师从凌开成教授,主要从事煤的高温快速液 化和气体脱硫等方面的研究。电话:138********,E -mail:gaoyane_2007@sina .com 栲胶脱硫法与改良ADA 脱硫法的比较 高艳娥,凌开成,牛艳霞,王艳领,马连华 (太原理工大学化学化工学院,山西太原　030024 摘　要:实验比较了栲胶法脱硫与改良ADA 法脱硫,讨论了脱硫效率、碱耗量和副产物Na 2S 2O 3含量随脱硫时间变化的情况。结果表明,两种方法的脱硫效率都很高,连续脱硫10h,也都在99.87%以上。从脱硫效率来看,两方法均能达到脱硫要求,但栲胶法比改良ADA 法略好。从碱耗量和副产物Na 2S 2O 3含量来看,改良ADA 法远比不上栲胶法。尽管实验装置与实际生产存在着一定的差距,但所取得的实验数据也能真实地反映出这两种脱硫方法的差异。 关键词:栲胶脱硫法;改良ADA 脱硫法;脱硫效率;碱耗 中图分类号:T Q 021.9　　　文献标识码:A 　　　文章编号:1671-3206(200804-0382-03 Co mpar ison between method of desulfur i zati on by t ann i n extract and method of modi fi ed ADA desulfuri zati on G AO Yan 2e,L IN G Ka i 2cheng,N IU Yan 2x ia,WAN G Yan 2ling,MA L ian 2hua (College of Che m istry and Chem ical Engineering,Taiyuan University of Technol ogy,Taiyuan 030024,China Abstract:I n the paper,desulfurizati on by tannin extract and modified ADA desulfurizati on were com 2pared,the change trends of the desulfurizati on efficiency,alkali consump ti on and by 2p r oducts (Na 2S 2O 3vs .ti m e is discussed .The conclusi on fr om the experi m ent is high desulfurizati on efficiency in both meth 2ods,even continuous desul phurizati on 10h,desulfurizati on efficiency was both over 99.87%.According t o desulfurizati on efficincy,the both methods can meet desulfurizati on require ments .But the tannin extract method is better than modified ADA p r ocess if alkali consump ti on and by 2p r oduct (Na 2S 2O 3are consid 2ered .A lthough there exists certain gap bet w een experi m ent and p ractical p r oducti on,the different bet w een the t w o methods can be really reflected using the obtained ex peri m ental data . Key words:method of desulfurizati on by tannin extract;method of modified ADA desulfurizati on;desul 2furizati on efficiency;alkali consump ti on 　　我国煤炭蕴藏丰富,21世纪煤化工发展前景看好。为了加强环保,充分利用焦炉气加工成化工产品和提供清洁的燃料气,焦炉气的脱硫净化显得尤为重要。国内焦炉气脱硫是以湿式氧化催化法为主[1]