高分子材料加工技术专业英语Photostabilizerslightstabilizer讲稿.docVIP

PAGE 3 PAGE 3 光稳定剂——light stabilizer 教学设计  教学内容与设计 时间分配 或备注说明 Photo degradation can Break of chemical bond of polymer molecules,lead to chalking and cracking of the polymer. How can we deal with this problem? The answer is Photo/light stabilizers 一、Mechanism of photo stabilization Physical reaction 1) Shield or reflect the UV radiation 2) Absorb the UV radiation 3) Extinguish the excited molecule The general name of this kind of light stabilizer is UV absorbers (UV As) Function: UVAs slow down the degradation process by preferentially absorbing harmful ultraviolet radiation and dissipating it as thermal energy Hindered amine light stabilizer (HALS) Function: HALS does not absorb UV radiation, but acts to inhibit degradation of the polymer. 二、Chemical reaction Advantages: Effective and efficient, significant levels of stabilization are achieved at relatively low concentrations. HALS’ high efficiency is due to a cyclic process wherein the HALS are regenerated rather than consumed during the stabilization process. 三、Typical light Stabilizer Hindered amine light stabilizer (HALS) HALS have synergistic effect with a lot additives, such as hindered phenolic antioxidant, UV light absorber et al. HALS is mainly used in polyolefin. The synergistic effect of HALS For example, for the paints for cars, when 0.5% HALS and 0.5% Benzotriazole are added, 50% gloss can be maintained after 2 years sunshine, while for the samples with 1.0% HALS or 1.0% Benzotriazole 50% gloss is reserved afer 1 year. However, without light stabilizer,more than 50% gloss is lost within 1 year. UV Shielding agent This kind of stabilizers can reflect or absorb all wavelength of sunlight,so it protect the polymer from UV radiation .This type of photo stabilizer mainly include carbon black, titanium dioxide, Zinc Oxide and so on. UV absorbers: UV absorbers are the light stabilizers with maximum consumption and longest history, it can absorb the UV radiation with the wavelength range from 290~380nm