《无机化学》课件-119_Chapter-12CoordinationCompounds-lecture2.pptVIP

Chapter 12Coordination CompoundLecture 2 Coordination compounds were originally named after the person who first prepared them or from their color, and some of these common names are still used, but most coordination complexes are named systematically through a set of rules by the International Union of Pure and Applied Chemistry (IUPAC):12.1.3 Nomenclature of CC (IUPAC Rules) 1. General RolesK4[Fe(CN)6]: potassium hexacyanoferrate(II)[Co(NH3)6]Cl3: hexaamminecobalt(III) chloridee.g.[Co(NH3)5Cl]2+Pentaamminechlorocobalt (III)五 氨 氯 钴 (III) As in simple ionic compounds, the positive ion is named first, followed by the negative ion, regardless of which is the complex ion. (This is a familiar rule.) 2. Names about Ligandsprefix number Mono-1Di-2Tri-3Tetra-4Penta5Hexa-6Hepta-7Octa- 8Nona-9Deca-10 In naming a coordination  complex, the ligands are  named first, and the metal in  the complex is named last,  followed by the oxidation  number of the metal as a  Roman numeral in  parentheses. The name of the  complex is written as one  word. The complete ligand  name consists of a Greek  prefix denoting the number  of ligands, followed by the  specific name of the ligand. (1) Names of LigandsThe names of anionic ligands are changed by replacing the usual ending with the suffix -o.The names of neutral ligands are unchanged.Three common neutral ligands are exceptions to this rule:  aqua → water,  ammine → ammonia carbonyl → carbon monoxide. ? The names of anionic ligands end with the suffix -o-ide suffix changed to -o-ite suffix changed to -ito-ate suffix changed to -atoLigandNamebromide, Br-bromochloride, Cl-chlorocyanide, CN-cyanohydroxide, OH-hydroxooxide, O2-oxofluoride, F-fluoro LigandNamecarbonate, CO32-carbonatooxalate, C2O42-oxalatosulfate, SO42-sulfatothiocyanate, SCN-thiocyanatothiosulfate, S2O32-thiosulfatoSulfite, SO32-sulfito