《无机化学》课件-122_Chapter-12CoordinationCompounds-lecture3.pptVIP

Inorganic Chemistry Chapter 12 Coordination Compounds Chapter 12 Coordination Compound Lecture 3 — theory of bonds between metal atoms and donor atoms 12.4 Valence Bond Theory of Coordination Compounds ? main valence and auxiliary vanlence theory (主价副价理论) ? valence bond theory(价键理论) ? crystal field theory(晶体场理论) ? molecular orbital theory(分子轨道理论) ? coordination field theory(配位场理论) Werners name will always be associated with the theory of coordination which he established and with his work on the spatial relationships of atoms in the molecule, the foundations of which were laid in the work he did, when he was only 24, for his doctorate thesis in 1892. In this work he formulated the idea that, in the numerous compounds of tervalent(三价的) nitrogen, the three valence bonds of the nitrogen atom are directed towards the three corners of a tetrahedron, the fourth corner of this being occupied by the nitrogen atom. Alfred Werner (1866 - 1919) 1913 Nobel Prize in chemistry In 1891 he had published a paper on the theory of affinity and valence, in which he substituted for Kekulés conception of constant valence, the idea that affinity is an attractive force exerted from the centre of the atom which acts uniformly towards all parts of the surface of the atom. Some Coordination Compounds of Cobalt Studied by Werner Werner’s Data* Traditional Total Free Modern Charge of Formula Ions Cl- Formula Complex Ion CoCl3 6 NH3 4 3 [Co(NH3)6]Cl3 3+ CoCl3 5 NH3 3 2 [Co(NH3)5Cl]Cl2 2+ CoCl3 4 NH3 2 1 [Co(NH3)4Cl2]Cl 1+ CoCl3 3 NH3 0 0 [Co(NH3)3Cl3] --- . . . . L· Pauling H· Bethe J· H· Van Vleck Valence bond theory 1931年 Crystal field theory 1929→1950S 20s of 20 century C