《无机化学》课件-126_Chapter-12CoordinationCompounds-lecture5.pptVIP

Chapter 12Coordination CompoundLecture 5 [Cu（NH3）4]2+add a little NaOH add a little Na2S no obvious changeblack solidKsp(Cu(OH)2)=5.6×10-20Cu(OH)2 IP KspKsp(CuS )=6.3×10-36CuS IP Kspreason： dissociation still occurs in coordination ion.12.6 Equilibria Involving  Complex Ions kf=[Cu(NH3)42+][Cu2+][NH3]4Kf — Formation constant of cc (also called  the stability constant, Ks) 12.6.1 Equilibrium of CC1. Kf and Kd of coordination compounds Cu2++4NH3 [Cu(NH3)4]2+ kformation kdissociation Kf2 [Cu(NH3)2]2+ [Cu(NH3)]2+ ＋ NH3each step with its own formation constant, Kfi , which is called the stepwise formation constant (or stepwise stability constant). Kf4 [Cu(NH3)4]2+ [Cu(NH3)3]2+＋ NH3 Kf3 [Cu(NH3)3]2+ [Cu(NH3)2]2+ ＋ NH3 Kf1Cu2+＋ NH3[Cu(NH3)]2+Actually, [Cu(NH3)4]2+ is formed in steps : Kf = Kf1×Kf2×Kf3×Kf4 = 1Kd Cu2++4NH3 [Cu(NH3)4]2+ kformation kdissociation Kf — the overall formation constant,  or simply the formation constant. Notice that：? the Kf values are all 106 or greater, meaning that  these ions form very readily. ? The larger the Kf , the more stable the complex  ion for ions of the same coordination number. ? For the different coordination number, compare  the stability of the complex by calculation. Comparison of stability of CC ions: Ks [ Mn+ ] （1）same type：■ Ag(NH3 )2+ 1.1× 107 9.1× 10-9 ■ Ag(CN)2- 1.3× 1021 7.7× 10-23（2）different type：■ CuY2- 6.3×1018 1.3× 10-10 ■ Cu(en)22+ 4×1019 8.6× 10-8 Sample Problem 12-1Calculating the Concentration of a Metal Ion in Equilibrium with a Complex Ion What is the concentration of Ag+(aq) ion in 1L 0.010 mol