天然气中酸性组分含量升高的脱硫系统优化研究.docxVIP

学兔兔 www . xue t ut 石 油 与 天 然 气 化 工 第43卷 第5期 CHEMICAL ENGINEERING OF OIL GAS 467 天然气中酸性组分含量升高的 脱硫系统优化研究 油气处程写加工范 峥1 刘向迎1 黄风林1 李稳宏2 乔玉龙3 闰 昭3 油气处程写加工 (1.西安石油大学化学化工学院) (2.西北大学化工学院 3.长庆油田第一采气厂) 摘 要 针对近年来天然气中酸性组分含量升高导致的产品气气质下降、设备故障频繁等问 题，利用 Aspen HYSYS软件对 MDEA 溶液循环量提高后的脱硫系统进行了流程模拟。结果表 明，当原料气中酸性组分 CO? 和 H?S 的体积分数分别由5 .280%和0 .028%增至6 .280%和 0.052%时，为了保证产品气符合国家标准，需将系统中的 MDEA 溶液循环量由63.25 m3/h 逐渐 提高至102.85 m3/h。 使用 Tray Rating、HTRI Xchanger Suite 软件对不同MDEA 溶液循环量下 的塔器和换热器等重要设备进行了一系列优化。经计算，胺液吸收塔和再生塔的流体力学性能均 符合要求；胺液贫富液换热器在 MDEA 溶液循环量提高时可串联1台同型号换热器，同时更换换 热管规格，以满足系统需要并缓解堵塞；优化后的二级闪蒸装置能够较大程度地缓解装置频繁波动 的情况，而在其入口处加装高效波纹板除沫器则可有效避免系统发泡。 关键词 天然气 脱硫 H?S CO? 甲基二乙醇胺 流程模拟 中图分类号：TE644 文献标志码：A DOI:10.3969/j.issn.1007-3426.2014.05.001 Optimization of desulphurization system for increased acidic components content in natural gas Fan Zheng,Liu Xiangying, Huang Fenglin,Li Wenhong2, Qiao Yulong3,Yan Zhao3 (1.College of Chemistry Chemical Engineering,Xian Shiyou University, Xian 710065, Shaanxi, China; 2. College of Chemical Engineering, Northwest University, Xian 710069, Shaanxi, China; 3. The First Gas Plant, Changqing Oilfield,Yulin 718500,Shaanxi,China) Abstract: Aiming at the inferior product gas quality and frequent equipment troubles due to the increase of acidic components content in natural gas in recent years, the process of desulphur- ization system after the increase of MDEA solution circulation flow rate was simulated by Aspen HYSYS software. The simulation result demonstrated that it was necessary to increase MDEA solution volume flow rate gradually from 63.25 m3/h to 102.85 m3/h to satisfy national stand- ards when the volume fraction of CO2 and H?S was increased from 5.280% and 0.028% to 6.280% and 0.052% respectively. Key facilities were i