一种红光材料的制备、光学性能及其在LED中的应用.docVIP

  一种红光材料的制备、光学性能及其在 LED 中的应用# 封科军1，李心恬2，方红2，邵光3** 5 10 15 20 25 30 35 40 （1. 惠州学院化学工程系，广东 惠州 516007； 2. 深圳市出入境检验检疫局工业品检测技术中心，广东 深圳 518017； 3. 中山大学化学与化学工程学院，广州 510275） 摘要：用一个含二苯乙炔的 β-二酮类配体和 1，10-邻啡罗啉作为第二配体来制备一个新的 三元 Eu(III)配合物。这个配合物具有较高的热稳定性，同时测定了一些光学性能包括红外、 紫外、激发和发射光谱、荧光寿命曲线和量子产率。将配合物与 395 nm 发射的 InGaN 芯片 相组合来获得一个发红光的二极管。二极管的发光光谱表明 InGaN 芯片发出的 395 nm 的光 可以完全被配合物所吸收。该器件的色坐标为 x = 0.6629, y = 0.3309，光效为 2.35 lm/W。这 个铕(III)配合物可被当作一个潜在的红色发光组分来应用于制备白光 LED。 关键词：有机化学；铕配合物；红光材料；光学性能；发光二极管 中图分类号：O69 Synthesis and Photophysical Properties of a Red-Emitting Material Applied in LED FENG Kejun1, LI Xintian2, FANG Hong2, SHAO Guang3 (1. Department of Chemical Engineering, Huizhou University, GuangZhou HuiZhou 516007; 2. Testing and Technology Center for Industrial Products,Shenzhen Entry-Exit Inspection and Quarantine Bureau, GuangDong ShenZhen 518017; 3. School of Chemistry and Chemical Engineering, Sun Yat-Sen University, GuangZhou 510275) Abstract: A new europium(III) ternary complex based on a diphenylethyne β–diketonate ligand and 1,10-phenanthroline as an ancillary ligand have been prepared. The complex exhibits a high decomposition temperature. Photophysical properties such as FT-IR spectra, UV-Vis absorption spectra, excitation and emission spectra, luminescence decay curve and quantum yield were investigated. An intense red-emitting LED was fabricated by coating the complex onto a 395 nm-emitting InGaN chip. The light emission from the InGaN chip could be completely absorbed in the spectrum of LED. An efficiency of 2.35 lm/W was achieved by coating the complex onto a 395 nm-emitting InGaN chip. Its Commission International de I’Eclairage (CIE) chromaticity coordinate is x = 0.6629, y = 0.3309. All the results conclude that the europium(III) complex is a promising candidate as a red component for near UV-based white LEDs. Keywords: Organic Chemistry; Europium(III) Complex; Red-Emitting Material; Photophysical Properties; Light-Emitting Diode 0 引言 白光 LED 作为一种新型的绿色环保型固体照