一个具有新颖三维开放骨架结构的磷酸铍化合物的合成.docVIP

  The Synthesis and Structure of a Novel Three-Dimensional Open-Framework Beryllophophate# GUO Min1, LI Yi2** 5 10 15 20 25 30 35 40 (1. Jilin University Library, Jilin University, ChangChun 130012; 2. State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, ChangChun 130012) Abstract: In this paper, a beryllophosphate (Be1.5PO5H2, compound 1) with netrual interrupted three-dimensional open-framework has been prepared with the addition of 2-aminoethanol under mild hydrothermal conditions. The structure of compound 1 is build up from two-dimensional 3.4-nets, which are further linked togother through BeO2(H2O)2 tetrahedra resulting in the final 2,4-connected three-dimentional open framework with 8-ring channels along the [010] direction. Crystal data: monoclinic, space group: C2/c (no. 15) with cell parameters of a = 15.964(3) ?，b = 4.5812(9) ?, c = 9.5377(19) ?, β = 94.42(3)°, and Z = 8. Keywords: inorganic chemistry; beryllophosphate; open framework; hydrothermal synthesis 0 Introduction Crystalline microporous open-framework compounds are of great importance with respect to their widespread applications in catalysis, ion exchange, and separation.[1] The discovery of microporous aluminophosphates in 1982, designated AlPO4-n promoted the enormous growth of open-framework metal phosphates.[2] So far, a large number of open-framework main group metal phosphates, such as aluminophosphates, gallium phosphates, indium phosphates, and beryllium phosphates, and various open-framework transition metal phosphates, such as manganese phosphates, cobalt phosphates, zinc phosphates, have been successfully prepared under hydrothermal/ solvothermal conditions in the presence of organic amines or inorganic cations as the structure-directing agents or space-filling agents. Among them, beryllium phosphates have attracted much more attention for their interesting structural diversity and low-density frameworks. Be2+, as the li