羧酸铕配合物光致发光薄膜的制备及研究.pdfVIP

羧酸铕配合物光致发光薄膜的制备及研究 摘 要 本文系统总结了稀土材料的特性和分类，介绍了稀土金属材料薄膜的发展概 况。全面综述了稀土光致发光材料的发光机理、制备方法以及应用。Eu 在紫外 光的作用下能够激发出红光。详细讨论了羧酸铕配合物薄膜的制备方法，深入研 究了喷雾热分解法制得的羧酸铕配合物薄膜的几个性能。本论文的工作主要包括 以下几个方面: 文中概括了稀土材料的特性以及稀土材料的分类，目前常用的镀膜方法主要 有溶胶凝胶和反应磁控溅射等方法，溶胶凝胶法薄膜厚度难以控制，磁控溅射需 要复杂的真空设备，成本较高，限制了镀膜在工业上的大规模生产。喷雾热解法 具有沉积温度、速率容易控制，对基板选择性低，所得薄膜形貌均匀致密等特点。 而且设备简单，成本低廉，在大规模工业生产方面有很大潜力。 利用甩胶喷雾热解法，以透明玻璃片为基板进行薄膜的制备。通过改变工艺 参数获得了不同条件的羧酸铕配合物薄膜。研究了这些薄膜发光强度和形貌的影 响，结合薄膜的形成过程深入探讨了喷雾热解法的机理。并通过分析不同制备条 件下薄膜的性能，研究了薄膜性能和制备条件之间的关系。 本工作表明使用喷雾热解法可以有效的实现羧酸铕配合物镀膜玻璃的制备， 从而为高效制备高质量薄膜提供一定的理论指导。 关键词: 甩胶喷雾热解法，稀土金属配合物，光致发光 II 羧酸铕配合物光致发光薄膜的制备及研究 Abstract In this article, The characteristic and classification of Rare-earth metal materials were discussed and the mechanism preparation and applications of Eu complexes film were also reviewed. The photoluminescence measurements exhibited red light-emitting characteristic of europium (III) coordination polymer. We mainly studied the preparation of Eu complexes film. The first part of the dissertation focuses on the characterization and classification of Rare-earth metal materials. The mechanism, preparation and applications of Rare-earth metal complexes. The circumgyrate spray paralysis method has large application potency to be a method to prepare the economical thin films for its unsophisticated equipment, low-cost and high deposition rate which are great advantages if the technique is to be scaled up for industrial applications. Rare-earth metal complexes films with super photoluminescence activity were deposited onto soda-lime glass using the spray pyrolysis method. Key Words: Circumgyrate sp