稻壳热解机理及气化试验研究.doc

南昌航空工业学院硕士学位论文  稻壳热解机理及气化试验研究 摘 要  2006 年 5 月  采用稻壳为实验原料，在管式炉中 N2 氛下，对生物质的热解气化产物进行了研 究。实验结果表明稻壳气化的适宜温度应在 800℃左右。当温度超过 800℃以后，气 化效率、碳转化率、产气热值等指标均呈下降趋势。气体产物中的 CO、H2 和 CO2 的 含量受热解温度的影响显著，而 CnHm 受温度的影响较小。 N2 氛下，在不同的加热速率(5、10、20 和 40K/min)下对稻壳进行了热重分析(TGA) 实验，对稻壳的失重行为进行研究。对 TG 和 DTG 曲线的分析结果表明，稻壳的热 解行为在加热速率低于 10K/min 时，主热分解可以分成两个明显的反应阶段，而高于 20K/min 时，主热分解变成一个阶段。升温速率影响物料开始热解的温度以及热解的 温度范围，升温速率的提高有利于生物质的热解反应。用 Malek 法将实验曲线与 20 种常用的固态反应动力学模型的标准曲线进行对比来选择最可几的机理函数(MLF)， 然后用 Li Chung-Hsiung 法对选择产生的最可几机理函数进行拟合，并以 MKN 法进 行最终确定。结果表明可以用模型函数 G(? ) ＝ (1???? ) ln(1???? )???? 来较好的描述，并根 据模拟结果求出活化能 E 和指前因子 A。  关键词：生物质  稻壳  热解气化  热重分析  动力学模型  1 南昌航空工业学院硕士学位论文  稻壳热解机理及气化试验研究  2006 年 5 月  Abstract The pyrolysis of husk was studied with the fir bits. The result of the pyrolysis indicated that if the intention was gas then the best pyrolysis temperature was about 800℃, which meant the optimist temperature of husk gasification was about 800℃. As the temperature ascended above 800℃, the efficiency of gasification, carbon conversion and calorific value descended gradually. Component of the gas was rather complex, mainly including CO2, CO, H2, CH4 and CnHm, among which CO, H2, and CO2 were affect by the pyrolysis temperature obviously，while CH4 and CnHm were affect by the temperature much less. Thermo-gravimetric analysis (TGA) experiment was used to study the mass loss of husk at different heating rate (5K/min, 10K/min, 20K/min, 40K/min) under nitrogen atmosphere. The analysis result of the TG and DTG curve showed that, if the heating rate was less than 10K/min, pyrolysis of the husk could be divided into two reaction stages, otherwise pyrolysis of the husk showed only one reaction stage, which indicated that the heating rate influenced not only the initiative temperature and the temperature range of pyrolysis, but also the reaction stage. Enhanced heating rate was more favorable to the pyrolysis of husk. In the light of the method of Malek, twenty typical functions of pyrolysis react