Mg-Al水滑石再生功能及催化活性的研究.pdfVIP

Mg-Al 水滑石再生功能及催化活性的研究* 赵策，曾虹燕*，李玉芹，刘跃进，刘平乐 (湘潭大学化工学院，湖南 湘潭 411105) 摘要：采用尿素法合成高结晶度 Mg-Al 水滑石(MAH) 。通过 XRD 、IR 、SEM、DSC 以及去卷积分析对 MAH 、再生“记忆”MAH (RMAH) 以及MAH 的金属氧化物(MAO)、RMAH 的金属氧化物(RMAO)进行表 征分析。结果表明，再生的“记忆”RMAH 和前体MAH 均具高结晶度水滑石层状晶体结构特征，两者晶 体结构和层板电荷密度几无差异。MAO 的层状结构依然存在，而RMAO 中存在MgAl2O4 物相，层状结构 完全消失。Hammett 指示剂法测定样品碱强度和总碱量显示：MAORMAORMAHMAH 。Mg-A1 LDOs(MAO 和 RMAO) 因具有更大碱强度和较多的活性位点使其催化制备生物柴油活性比 Mg-A1 LDHs(MAH 和RMAH)大幅提高。再生的RMAH 由于碱强度增大，其催化制备生物柴油活性较MAH 略 有升高。RMAO 层状结构完全消失产生较多MgAl2O4 物相导致部分活性中心失活，同时碱强度降低，催化 制备生物柴油活性较MAO 降低。 关键词:水滑石；再生；碱强度；生物柴油；催化活性 中图分类号: 文献标示码: A 文章编号: A study of Mg/A1 hydrotalcites reconstruction properties and catalysis biodiesel reaction * Zhao Ce Zeng Hongyan Li YuQin Liu Yuejin Liu Pingle (School of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan) Abstract: Mg-Al hydrotalcite(MAH)with a high crystallinity was prepared by urea method. The MAH, reformed MAH(RMAH), calcined MAH(MAO)and calcined RMAH(RMAO)were determined by XRD、IR、SEM and DSC via self-deconvolution analyses. The results showed that the MAH and RMAH possessed a layered structure of hydrotalcites with high crystallinity, and there was little difference in crystal structure and charge density of the brucite-like sheets between MAH and RMAH. The brucite-like sheets still existed in MAH, but disappeared in RMAH with MgAl O phase. Mensurate the samples’ basicity and total basicity using Hammett indicator method: 2 4 MAORMAORMAHMAH.The catalysis activity of Mg-A1 LDOs(MAO 和 RMAO) to biodiesel was substantially higher than that of Mg-A1 LDHs(MAH 和RMAH), mainly resulting from the “memory effect” of Mg-A1 LDOs has higher basicity and more activity point.The reconst