常温合成聚羧酸减水剂工艺研究.pdfVIP

常温合成聚羧酸减水剂工艺研究 孙远王浩逄建军张力冉王栋民 (中国矿业大学北京100083) 摘要：以TPEG，AA为原料，通过自由基聚合的方法合成聚羧酸减水剂。文章 研究了合成温度及引发剂用量对聚羧酸减水剂分散性能的影响。结果表明：在合 成配比不变的条件下，随着合成温度的升高，水泥净浆流动度增加，聚羧酸减水 剂对水泥颗粒的分散能力增强；合成温度为20C、40。C时，引发剂用量与聚羧 酸减水剂的分散性能呈正相关。其中，合成温度为20℃时，引发剂用量较敏感， 且减水剂的分散能力较差；合成温度为40。C时，在低引发剂用量下水泥经时损 失较大。 关键词：常温；聚羧酸减水剂；引发剂用量；自由基聚合 of atroom Studypolycarboxylatesuperplasticizers’synthetictechnologytemperature Hao Liran Wang PangJianjunZhang WangDongmin of and 1 (ChinaUniversityMiningTechnologyBeijing 00083) Abstract：AuthorTPEG，AAasrawmaterialto regarded synthesis polycarboxylate tofreeradical wasstudiedthe superplasticizeraccording polymerization．Thispassage effectof ofthe andtheinitiator on temperaturesynthetic dosagesuperplasticizers’ result shows：asthe increased，theofcement performance．The temperature fluidity isincreased，SOasto tocement is paste superplasticizer’Sdispersionability particle enhanceundertheconstant ratioof the for20 synthesis；whensynthesistemperature ℃and40。C，theinitiator and the of dosage dispersionpropertiessuperplasticizer were ofwhich correlated， theinitiator issensitiveand positively dosage showing of at low ofinitiatorthe ability poordispersion superplasticizer20。C；Underdosage