增钙煤矸石地火山灰活性研究.pdfVIP

增钙煤矸石的火山灰活性研究 1 2 1 宋旭艳 ，李东旭，韩静云 1.苏州科技学院土木工程学院 苏州 215011 2.南京工业大学材料科学与工程学院 南京 210009 摘 要：在原样煤矸石的分析基础上，提出一种合适的增钙活化煤矸石样，并对其进行火山灰活性的测 定。结果表明：在煤矸石的增钙活化过程中掺入适量的石膏和萤石等组分作为矿化剂时，能生成较多的水 硬性矿物且其火山灰活性较佳；活性评定试验表明： 在增钙活化煤矸石与氧化钙的复合体系中，Ca(OH)2含 量和化学结合水量随龄期的变化规律与其水化过程的结构特征是一致的。 关键词：增钙煤矸石；火山灰活性；Ca(OH) 含量；化学结合水量；微结构分析 2 + 中图分类号：TQ172.71 6 Study on Pozzolanic Activity of Added-Calcium Coal Gangue 1 2 1 SONG Xuyan , LI Dongxu , HAN Jingyun 1. College of Civil Engineering, University of Science and Technology of Suzhou, Suzhou 215011 2. College of Material Science ＆ Engineering ，Nanjing University of Technology, Nanjing 210009 Abstract After analysis on raw coal gangue, added-calcium coal gangue can be introduced. Again, its pozzolanic activity may be analyzed. The results show that when proper amount of gypsum and fluorite were taken as for mineralizer in the course of calcinations of calcium-doped coal gangue, much mineral with hydrated setting can come into being and its pozzolanic activity can behave very well. The experiment of activity evaluation can approve: the change on structural characteristic of hydration process of added-calcium coal gangue with lime is consistent basically with that of Ca(OH)2 content and chemically combined water. Key words added-calcium coal gangue; pozzolanic activity; Ca(OH)2 content; chemically combined water; microstructure study 0 前 言 未经处理的煤矸石具有稳定的硅酸盐晶体结构，其胶凝活性很低。但通过物理活化、化 学活化、热活化及增钙活化等方法可使煤矸石废弃物具有一定的火山灰活性，使其成为有用 的无机胶凝材料[1]~[3] 。本文以徐州煤矸石为研究对象，研究了经增钙活化后的煤矸石的化学 反应活性特征，并通过石灰吸收法和化学结合水法对其进行活性评定[4]~[